Manuel Orlandi
@ManuelOrlandi87
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Happy to share my last work at @discunipd in which we exploit a CuH-catalyzed intramolecular hydroalkylation of γ-bromocrotonates for the enantioselective synthesis of cyclopropanes on @ACSCatalysis. @ManuelOrlandi87 @GiuliaLicini1 @LundbeckItalia.
pubs.acs.org
A Cu-catalyzed cyclopropanation of γ-bromocrotonate derivatives via a hydrocupration–alkylation sequence is described. This hydroalkylation process is of good generality and allows access to chiral...
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Out in @J_A_C_S a couple of equations to accurately predict the activity of Cu complexes in atom transfer radical reactions. Another (the last?) project that started in @MatyPolymerLab but evolved in unexpected ways. Also with @EAEG_Unipd @MarcoFantinChem
pubs.acs.org
In catalysis, linear free energy relationships (LFERs) are commonly used to identify reaction descriptors that enable the prediction of outcomes and the design of more effective catalysts. Herein,...
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Check out the #OpenAccess work by @ManuelOrlandi87 on the Co(Salox)-catalyzed enantioselective reduction of alpha,beta-unsaturated esters, part of our #NextGenOrgChem special collection. Nominated by our Board Member @LucaDellAmicoLD
https://t.co/olRXB8gaW9
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Co(Salox)-Catalyzed Enantioselective Reduction of alpha,beta-Unsaturated Esters by @ManuelOrlandi87 and co-workers (@DiSC_UniPD @SCIorganica @GiuliaLicini1) #OpenAccess #NextGenOrgChem
https://t.co/vrMUCCnMv2
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The first paper of the group is out!! Congrats @chem_korzun and thanks to @stefano_crespi for the fruitful collaboration. Replacing the BO in BODIPY: Unlocking the Path to SBIDIPY and BIDIPY Chromophores https://t.co/6aJ4JlitS6
@ChemRxiv #SBIDIPY #BIDIPY
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Catalytic Asymmetric Conjugate Reduction (Orlandi) @ManuelOrlandi87 @DiSC_UniPD #AngewandteReview #openaccess
https://t.co/lFXMU9CWoK
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Our adventure with PCET contiues! Happy to contributo to the @JOC_OL special issue in photocatalysis! Thanks to Munetaka Akita, @Ceroni_GROUP and @crjsteph @StephensonLabUM for the invitation!!! A great collaborative work with @asartorel74 !!! 👉 https://t.co/cJ7PcQiQFQ
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Congratulations to @jordiduran6 for a titanic effort! His first PhD work is out in @ChemRxiv, focusing on the Catalytic Asymmetric Defluorinative construction of alpha-Allyl Ketones. Kudos also to @javiml_94 @UniBarcelona @QuimicaUB Check it out here 👉 https://t.co/5IkNH6wj1e
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The Next Generation Perylenebisimide “Quantasomes” | Journal of the American Chemical Society @J_A_C_S @DiSC_UniPD @itmcnr @nanomolcat 🌞🌞🌞🌞
pubs.acs.org
As the natural-born photoelectrolyzer for oxygen delivery, photosystem II (PSII) is hardly replicated with man-made constructs. However, building on the “quantasome” hypothesis ( Science 1964, 144,...
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Curious to see how tartaric acid content in wines could be determined using #supramolecular #cages and circular dichroism? Check out our latest work just published in @ACS_Sensor @RobertoPenasa @GiuliaLicini1 @ZontaCristiano
pubs.acs.org
The fundamental implications that chirality has in science and technology require continuous efforts for the development of fast, economic, and reliable quantitative methods for enantiopurity...
Straight from the bottle again! Check out this #cage #supramolecular sensor for tartaric acid, which uses circular dichroism. @federicobegato @RobertoPenasa @GiuliaLicini1 @ZontaCristiano @DiSC_UniPD
https://t.co/CCvUdwEmns
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Congrats to the team @tobiasgensch @gabepgomes @A_Aspuru_Guzik @robpollice and many others for building a unique, ML-enabled phosphine descriptor database!
pubs.acs.org
The design of molecular catalysts typically involves reconciling multiple conflicting property requirements, largely relying on human intuition and local structural searches. However, the vast number...
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Congratulations to Silvia Benavides-Varela, @LucaDellAmicoLD, Ludovica Galeazzo & @MarthaPamato! They won the #ERCStG competition and will be hosted at @UniPadova to carry out their research projects. In 🇮🇹, Unipd ranks first for funding provided! https://t.co/7B4jNN4gBj
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Congratulazioni ai vincitori @ERC_Research starting grants. Studiose/studiosi italiani in numeri assoluti secondi solo ai tedeschi (58)! Tuttavia l'Italia - dove far ricerca - rimane ben indietro (28) e dopo GER, FRA, UK, NL. Succede da anni, grave per il paese e la politica.
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Thrilled to share my #MASC2021Poster. Here we employed wines and juices straight from the bottle to template the self-assembly of our #supramolecular #cages. @MASC2021 @RobertoPenasa @GiuliaLicini1 @ZontaCristiano @ChemCommun
https://t.co/QsRCSDJaNf
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Very proud to share our thermodynamic analysis for predicting the reactivity of carbanions with carbon dioxide, now in @FrontChemistry: https://t.co/olWxTJmHAr This is also my first paper FREE of any transition metal: influenced @NanoMolCat by my friend @LucaDellAmicoLD ?! 🤔🤣
frontiersin.org
The utilization of carbon dioxide as a raw material represents nowadays an appealing strategy in the renewable energy, organic synthesis and green chemistry ...
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Congrats to Cian, Sleight, and Natalie and our fantastic collaborators @Genentech! Funded by @NSF_CCAS. We integrate #HTE and #datascience to develop a cross-coupling reaction
pubs.acs.org
We report the development of a method to diastereoselectively access tetrasubstituted alkenes via nickel-catalyzed Suzuki–Miyaura cross-couplings of enol tosylates and boronic acid esters. Either...
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“Excited to share the results of our collaboration with the @WizardsofOztin! Our study combines statistical modeling with dynamic covalent chemistry to make new chiroptical sensors”
pubs.acs.org
Dynamic covalent chemistry-based sensors have recently emerged as powerful tools to rapidly determine the enantiomeric excess of organic small molecules. While a bevy of sensors have been developed,...
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Don’t miss this #EurJOCReview discussing recent advances in the area of amide synthesis by @BenagliaLab (@LaStatale)! 👉 https://t.co/2cn6IC7JHj
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If you want to see how wines and juices templated our #supramolecular #cages self-assembly, check out our work just published in @ChemCommun. @RobertoPenasa @GiuliaLicini1
@ZontaCristiano @DiSC_UniPD
https://t.co/QsRCSDJaNf
pubs.rsc.org
Two imine based supramolecular cages are able to self-assemble in the presence of a complex mixture like wine or fruit juices. Taking advantage of templating agents present in these mixtures the...
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