Chemical Communications
@ChemCommun
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Urgent communications of outstanding significance. This account has been archived. Connect with us on https://t.co/EGnCNQD6Yl, LinkedIn, Bluesky and WeChat.
Cambridge, UK
Joined March 2009
Social media and connecting with our community – moving on from X. You can continue to find the latest news and updates from ChemComm on our other social media channels: Bluesky https://t.co/2v1ei4caYq LinkedIn https://t.co/KDmmRe3Hft
https://t.co/M6iSEm8Muk
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ICYMI, from @afukazawa79 and colleagues: 'Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion' https://t.co/As5VQ8X7j7
pubs.rsc.org
A dianionic species of a thienoquinoid derivative bearing a cross-conjugated γ-thiolactone, the so-called S-Pechmann dye, has been synthesized and characterized. Comparative analysis with a pentafu...
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New from Ellen Matson and Zhou Lu: 'Consequences of substituting framework metals in polyoxometalates on H-atom uptake: proton-coupled electron transfer at a Keggin-type polyoxomolybdate' @MatsonLab
https://t.co/J3aZya4eX4
pubs.rsc.org
The proton-coupled electron transfer to the surface of a Keggin-type polyoxomolybdate, [nBu4N]3[PMo12O40], is described. The thermochemistry of surface O–H bonds generated upon reduction/protonation...
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ICYMI, from @ckerzig, @GloriusFrank and colleagues: 'Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range' 🔥 #OpenAccess 🔓 https://t.co/Ail9Ug4Q8D
pubs.rsc.org
Triplet–triplet annihilation photon upconversion (TTA-UC) provides a milder alternative to traditional UVB/UVC photochemistry. However, suitable sensitizer-annihilator pairs are scarce, in particular...
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New review article from Anna Slater and colleagues at @LivUni: 'Self-assembly under continuous flow conditions' https://t.co/MBvsEQLdos
pubs.rsc.org
Self-assembly plays a crucial role in the formation of hierarchical supramolecular structures and functional materials. The use of flow chemistry for self-assembly processes has garnered significant...
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ICYMI, from @Faguang_Zhang and colleagues at Tianjin University: 'Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent to access 2-(difluoromethyl)naphthalene' https://t.co/knVyrvM99x
pubs.rsc.org
In this study, we design and synthesize a reactive difluorodiazo hypervalent iodine(III) reagent that facilitates the ring expansion of indene under mild basic conditions at room temperature. This...
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ICYMI, from Tomoyuki Mochida and colleagues at @KobeU_PR 'Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions' https://t.co/PPRUNeTVHv
pubs.rsc.org
Coordination compounds, including cage compounds, are typically synthesized via solution reactions. Here, we report the solvent-free, quantitative conversion of organometallic ionic liquids (ILs)...
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ICYMI, from Kiyosei Takasu, Hiroshi Takikawa and colleagues at Kyoto University: Take a look at 'Arylative double bond transposition of allylic alcohols via silicon-tethered intramolecular benzyne–ene reactions' @KUGousei
https://t.co/JNzzf6Js6V
pubs.rsc.org
Silicon-tethered intramolecular benzyne–ene reactions provide an efficient strategy for converting allylic alcohols into aryl-substituted homoallylic alcohol derivatives. This approach utilizes a...
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Check out this new article from Filipp Furche, William Evans and colleagues at @UCIChemistry on the four-electron oxidation and one-electron reduction of a bis(terphenylthiolate) U(ii) complex. https://t.co/uk7LWRV0Bs '
pubs.rsc.org
The utility of the sterically bulky terphenylthiolate ligand, (SAriPr6)1− in expanding uranium reductive chemistry has been explored. Reduction of U(SAriPr6)2I forms the U(ii) complex, U(SAriPr6)2,...
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ICYMI, from @mvdelius, Fedor Jelezko, Alexander Kuehne and co. 'Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence' 🔥 #OpenAccess 🔓 https://t.co/kPD1U5G6TT
pubs.rsc.org
Organic radicals and diradicaloids that are both stable and luminescent are promising candidates for molecular qubits in quantum technologies. Here we report two new carbazole-functionalized Chichi...
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New from Clare Mahon and colleagues at @DurhamChemistry 'An unexpected chlorination of an organic sunscreen' #OpenAccess 🔓 https://t.co/Qasus5bYv8
pubs.rsc.org
The origin of intense red staining on fabrics contaminated by sunscreen and treated with bleach has been attributed to an unexpected dichlorination of a common UV filter. The structure of the...
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ICYMI, from @sjgharpure and colleagues at @iitbombay 'Lewis acid-promoted cascade reactions of cyclopropenes: a unified approach to stereoselective synthesis of cyclic ethers and oxaspirolactones' https://t.co/sErON599pd
pubs.rsc.org
Lewis acid-promoted 5/6-exo trig hydroalkoxylation/reduction cascade of ω-hydroxy cyclopropenes gave expeditious, stereoselective access to THF/THP derivatives. Monoester substituted ω-hydroxy...
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New from @PutlaSudarsanam and colleagues: 'Catalytic imidazolysis of PET plastic waste using self-assembled NbOx nanorods' @SP_Heterocat
https://t.co/MlpjHHssVz
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New from Tomoyuki Mochida and colleagues at @KobeU_PR 'Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions' https://t.co/teMj9ePeE2
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New from @SharmaLabOU 'Iron-catalyzed iodonium ion promoted activation of conventional thioglycosides for stereoselective 1,2-cis furanosylations' #OpenAccess 🔓 https://t.co/yOLGYDK0HV
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New Review article from @gregory_chatel 'Scaling-up green chemistry: bridging innovation and industrial applications' https://t.co/2Dlo9yEaj0
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New from @Debdas_snu and colleagues: 'Charge transfer alteration and white light emission in photochromic triphenylamine-norbornadiene-triazine switch' #OpenAccess 🔓 https://t.co/Za116Vg42o
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New from @afukazawa79 and colleagues: 'Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion' https://t.co/As5VQ8X7j7
pubs.rsc.org
A dianionic species of a thienoquinoid derivative bearing a cross-conjugated γ-thiolactone, the so-called S-Pechmann dye, has been synthesized and characterized. Comparative analysis with a pentafu...
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ICYMI, from @CharlieFehl and Arun Thangarasu at @waynestatechem 'Thioglycoside functionalization via chemoselective phosphine acceleration of a photocatalytic thiol–ene reaction' #OpenAccess 🔓 https://t.co/3CO5avssMt
pubs.rsc.org
Thioglycosides are enzymatically stable carbohydrate variants used in biotechnology as probes and investigational drugs. To date, harsh activation conditions limit the scope of thiol–ene sugar...
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New Hot article from @ckerzig @GloriusFrank and colleagues: 'Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range' 🔥 #OpenAccess 🔓 https://t.co/LhYcLjqbfC
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