Bismuto Lab
@BismutoLab
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At the interface of Main Group and Transition Metal Chemistry
Joined October 2021
đHBT Herbert W. Roesky who turns 90 today. He studied chemistry at the University of Goettingen @uniGoettingen from 1957 onwards and earned his PhD in 1963 for work with Oskar Glemser on the high pressure #fluorination of metals. After a postdoc with Earl Muetterties in the
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Great news for Bonn!! We are looking forward to having you here!!
We are simply fluored that Florian Kraus (Marburg) will be joining us in Bonn! Florian, we look forward to welcoming you and your group in 2026. Life is about to become alot 99Mo-re F-U-N! #UniBonn #Inorganic
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Thanks for the amazing conference!! Fantastic organisation and scientific discussion!
to start the day 3, we have the first plenary lecture by @BismutoLab from @UniBonn . He will be showing us what happens when we shine light on dipnictenes. Fascinating right, enjoy!
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Many thanks for the great highlight!
Alessandro Bismuto, University of Bonn, and colleagues have synthesized and characterized three- and four-membered heterocyclic rings containing Sbâ- or Biâ-units, obtained from heavy dipnictenes (Sb=Sb, Bi=Bi) and different azides https://t.co/X4bieM0rzd
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We showed the activation of distibene and dibismuthene with a series of azides to generate small inorganic rings. The divergent reactivity has lead to an interesting example of NHC-stabilised imino-bismuthane.
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A new chapter in Small Inorganic Ring đđ§ȘCongratulation @Palui004 and all the coauthors for the great job. #Bismuth #Antimony
https://t.co/gQMXQ3hVUL
pubs.rsc.org
Small organic rings are important molecular entities that have long played a crucial role in organic synthesis and medicinal chemistry. Similarly, small inorganic rings have shown promise in promot...
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Thanks to the great collaborations with the Green, Grimme and Kornienko groups, we have been able to analyse the mechanism and investigate the effect of light during CV measurements and validate it using computational methods; check the SI for more infođđĄ
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Congrats André @chem_korzun and all the authors involved for this new generation of SBDIPY and BIDIPY and their application in photocatalysis! Now published in @InorgChem
https://t.co/0B4FRFBAUy
pubs.acs.org
The unique chemical reactivity offered by photochemistry has driven a growing interest in the design of new photocatalysts with diverse chemical properties. Incorporating heavy atoms into the core of...
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Donât miss the opportunity to join the new Women Mentoring Program organized by the #MedChem Division of the German Chemical Society (GDCh)! âłApplication Deadline: July 31st, 2025 For more information: https://t.co/1TivKqNr6A
#WomenInSTEM @GDCh_aktuell
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Fantastic conference this fall (17-19 September) near Vienna, Austria! The lineup at the âPhotoexciting Moleculesâ at the Institute of Science and Technology Austria (ISTA) is amazing!!! Check it out: https://t.co/4EeoXOQr2t
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We are happy to support postdoctoral applications for MSCA Postdoctoral Fellows and Humboldt research fellow to explore bismuth and antimony chemistry https://t.co/Zo5DfhluKF
https://t.co/wUaB60BLex
humboldt-foundation.de
Through the Humboldt Research Fellowship, the Alexander von Humboldt Foundation sponsors researchers with above-average qualifications from across the globe.
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The group is moving to bluesky soon - stay tuned and follow our research on @bismutolab.bsky.social đ§Șđ§Ș
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Many Thanks for the highlight!!
Heavier Analogs of 1,2-Dihydrotetrazole: Experimental and theoretical investigation of the first diazadistiboylidenes https://t.co/eMdvLAOg1m
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Glad to see this out in @cenmag !! Many thanks Beth for the amazing highlight! https://t.co/T8SdmLhfmo
cen.acs.org
Chemists create heterocycles with multiple antimony atoms, including a stable, 3-membered ring
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Looking forward to this event!!
The first Main-Group Elements Reactivity Conference "MGERC-1" will take place at the University of Namur @UNamurđ§đȘ on Sept 8-10. Confirmed speakers, abstracts, registration: https://t.co/krx0s9Ur0T. Thanks to the speakers, sponsors, @ERC_Research and @frsFNRS. Save the date / RT.
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Distibene, Diazoolefins, and Visible Light: Synthesis and Reactivity of Inorganic Rings | Journal of the American Chemical Society @AlexBismuto @bismutolab @unibonn - Study of diazadistiboylidenes made by cycloadiition of diazoolefins and distilbene-
pubs.acs.org
The chemistry of heterocycles containing âdiazaâ units has been extensively studied due to their applications ranging from pharmaceuticals to advanced materials. In contrast, heterocycles incorpora...
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A great Start of the year with the first @JACS of the group!! Synthesis of Heavy Inorganic Rings and their reactivityđ§Ș Congratulations to @Palui004 and Sangita and all other involved. Thanks to Toni Frontera for the fantastic collaboration. https://t.co/RYmqoaQMO1
pubs.acs.org
The chemistry of heterocycles containing âdiazaâ units has been extensively studied due to their applications ranging from pharmaceuticals to advanced materials. In contrast, heterocycles incorpora...
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And another in the same week! Our collaboration with Prof Mike Ingleson has been published in Angewandte @angew_chem as well. Read it below. https://t.co/eVT8x0swrX
onlinelibrary.wiley.com
Borane-mediated deoxyfluorination of in situ generated N-H-O-alkyl-isoureas using Et3Nââ
â3HF represents a novel approach to achieve a highly 2°-alcohol-selective substitution in preference to...
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A nice holiday present for us! Our most recent article has been accepted Angewandte @angew_chem. Read it at the link below. https://t.co/fayw5i9Q77
onlinelibrary.wiley.com
Mechanistic analysis revealed the iron-catalysed CâH borylation of 2-phenylpyridine derivatives with 9-borabicyclo[3.3.1]nonane ([H-B-9-BBN]2) operates through hidden catalysis with the iron salt...
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