María L. G. Sansores Paredes
@MariaLSP14
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Account not in use. Bluesky profile: msansoresparedes
VU Amsterdam
Joined February 2022
RT @J_A_C_S: Monodentate σ-Accepting Boron-Based Ligands Bearing Square-Planar Ni(0) Centers | Journal of the American Chemical Society @os….
pubs.acs.org
Transition metals are known to work as electron donors toward electron-accepting heavier-group-13 elements (Al, Ga, and In), called Z-type ligands. However, complexes with boron-based Z-type ligands...
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RT @J_A_C_S: Impact of Secondary Sphere Hydrogen Bonds on O2 Reactivity within a Nonheme Iron Complex | Journal of the American Chemical So….
pubs.acs.org
A nonheme iron complex bearing the tris(6-phenylamino-pyridyl)methylamine (TPANHPh) ligand with appended hydrogen bond (H-bond) groups displays facile O2 reactivity to form a monomeric Fe(III)OH...
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RT @ChemistryViews: New Class of Carbon-Centered Diradicals Discovered.Monosubstituted carbon atom stabilized by a phosphine shows a triple….
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RT @ME_Moret: Then, an unusual carbene transfer reaction to an isocyanide ligand was uncovered: . 3/3.
pubs.rsc.org
A formal carbene-transfer reaction from an isolated nickelacyclobutane to an isocyanide to form a ketenimine is reported. DFT calculations support a stepwise 1,1-insertion/fragmentation pathway...
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RT @ME_Moret: This concludes (for now) our study of the reactivity of a pincer nickelacyclobutane. First, it was shown to react along the l….
onlinelibrary.wiley.com
A pincer scaffold allows the isolation of a nickelacyclobutane and a detailed study of its reactivity. The cycle slowly undergoes an apparent beta-elimination reaction in non-polar solvents; exposu...
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RT @ME_Moret: The latest paper of @MariaLSP14 with Martin Lutz is now available online in its fully typeset form in @ChemEurJ : . https:….
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RT @ChemEurJ: Addition and Oxidation Reactivity of a Pentacoordinate Nickelacyclobutane (@MariaLSP14, Marc-Etienne Moret @ME_Moret and co-w….
chemistry-europe.onlinelibrary.wiley.com
The reactivity of a pentacoordinate nickelacyclobutane following addition and one-electron oxidation pathways is described. Ring-opening products are observed with substrates containing a stabilizi...
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Check out our last work on the reactivity of a pentacoordinated nickelacyclobutane! . #metallacyclobutane #organometallics #nickel.
What happens when you oxidize a metallacyclobutane? . The last #openaccess chapter of @MariaLSP14 's nickelacyclobutane saga has just been accepted in @ChemEurJ. Work done at @UU_ISCC and funded by @ERC_Research. Check it out! .
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RT @ME_Moret: What happens when you oxidize a metallacyclobutane? . The last #openaccess chapter of @MariaLSP14 's nickelacyclobutane saga….
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RT @LabBraunschweig: Check out Dhara's (@DharaChem) work on the catenation of aluminium, now out in @J_A_C_S .Thanks to @felipefantuzzi and….
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RT @ChemistryEur: Pd/S cooperativity: from stoichiometric activation of Si-H bonds to catalytic hydrosilylation by Blanca Martin-Vaca, Did….
chemistry-europe.onlinelibrary.wiley.com
A Palladium(II) complex equipped with a pincer-type PNS ligand is shown to readily activate hydrosilanes and to efficiently catalyze the hydrosilylation of alkynes. The key Si−H bond activation step...
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RT @SzymczakLab: Check out our recent paper in @ChemCommun showing increased Fe-N2 activation with a mixed NHC/phosphine ligand set. Great….
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RT @GroupAldridge: New collaborative papers in JACS! #1.Two collaborative studies on p-block chemistry featuring work from the group have j….
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RT @nz_molecules: Another old #ChemEd #Chemistry summary. This covers resonance. The 1st summary that led to interesting discussion (i.e. n….
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RT @ChemCommun: ICYMI, from @ME_Moret and first author @MariaLSP14 at @UU_ISCC. 'Carbene transfer reactivity from a nickelacyclobutane'. #O….
pubs.rsc.org
A formal carbene-transfer reaction from an isolated nickelacyclobutane to an isocyanide to form a ketenimine is reported. DFT calculations support a stepwise 1,1-insertion/fragmentation pathway...
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RT @ccdc_cambridge: Novel cases of strain-promoted cyclotrimerizations of alkyne CPPs to make pinwheel-like nanostructures are reported in….
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RT @claireeboone: Our new paper in @ScienceMagazine studies how exposure to sugar in utero and in early life affects risk of hypertension a….
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