The Braunschweig Group
@LabBraunschweig
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Organometallic and main group element chemistry research group. Located at the Institute of Inorganic Chemistry @Uni_WUE. Account managed by group members.
Univ. Würzburg, Germany
Joined February 2022
New from @Nele_Wie in @ChemicalScience! “Boraindenes as versatile precursors to benzannulated boron heterocycles.” Check it out! https://t.co/tvxKdne1bC Thanks to all contributors! #chemtwitter #Boron #UniWue
pubs.rsc.org
Five-membered boroles and their doubly benzannulated 9-borafluorene derivatives are established precursors for synthesizing a broad range of boron-doped heterocycles of broad applied interest....
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Sourav's work on direct interconversion between bis(borylenes) and diborenes is now published in @J_A_C_S − give it a read. Many thanks to all contributors!
Check out our latest work on 'Direct Interconversion between Bis(borylenes) and Diborenes', published in @J_A_C_S Many thanks to @KoushikSaha1991, @BinilkrishnaS, Ivo, Rian, and @LabBraunschweig! https://t.co/4bvj864ntB
#chemtwitter #boron #UniWue
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Can boron replace metal? Check out @maxi_michel_ and Marco’s latest work 'Olefin π-coordination chemistry at low-oxidation-state boron', now published in @NatureChemistry
https://t.co/uIFmry3NGb Thanks to all contributors! #chemtwitter #11B #UniWue
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Check out Christian's work on "Simple, one-step syntheses of tri- and tetracyclic B,N,S-heterocycles from reactions of a diboracumulene with thiols"-published in @ChemicalScience Many thanks to @kar_sourav, Lukas, Kai and Rian! https://t.co/obQ1BmEL2O
#chemtwitter #11B #UniWue
pubs.rsc.org
Boron-containing fused heterocycles have received considerable attention due to their unique structures, bonding, and intriguing properties. However, progress in this area has been hampered by a lack...
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I am happy to share that our latest paper has been published in @ScienceMagazine. In this work, we report the synthesis of novel tin carbonyl and carbene complexes. Thanks to all collaborators! https://t.co/y9kl9HwaTA
@GroupAldridge
@AvHStiftung
@OxfordChemistry
@UniofOxford
science.org
In contrast to transition elements, s- and p-block metal compounds that coordinate carbon monoxide (CO) under near-ambient conditions are elusive. Here, we report an isolable, crystalline main-group...
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Ring expansion through direct B–B bond carbonylation: Check out Eva's latest work, now out in @ScienceAdvances! Many thanks to all contributors! https://t.co/G152WoqrPb
#chemtwitter #11B #UniWue
science.org
Using carbon monoxide gas as a selective method for the direct production of bis(boryl)ketones.
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Nicola's work on oligoboranes, entitled as 'Atom-Efficient Synthesis of BN-Heterocycles from Oligoboranes and Isonitriles,' has now been published in @ChemCommun! Many thanks to all contributors! https://t.co/2w9tIIU4u3
pubs.rsc.org
O-Xylyl isonitrile readily inserts into one of the B–B bonds of simple, unactivated linear peraminotri- and tetraboranes. Subsequent thermal rearrangements yield two different types of CB2N heteroc...
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I am happy to announce that our paper on the reactivity of a neutral diboraanthracene has been selected for the @DaltonTrans 2024 Oustanding Paper Award! Thanks to all collaborators! @LabBraunschweig
https://t.co/alq7Hjyy6a
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We keep shining!✨@LeonieWuest´s and @Johannes_Chb´s follow-up paper on luminescent 1,2,3-diazaborinates is out now in @ChemicalScience. Thanks to the @HeltenGroup and all contributors for this luminescent coorporation! https://t.co/xs9vNvewXq
pubs.rsc.org
B-Aryl-based 1,2,3-diazaborinates (DABates), derived from neutral 1,2,3-diazaborines (DABs), are a promising class of unexplored fluorophores which show an intriguing high optical performance. This...
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Check out Marco's latest work on aromatic 1,4-Diboraanthracene, now out in @J_A_C_S Many thanks to all contributors! #chemtwitter #11B #UniWue
Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes | Journal of the American Chemical Society @Uni_WUE
@LabBraunschweig
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Ring expansion vs ring opening: Check out Eva’s newest work on Boron-chalcogen heterocycles and linear tetraboranes from a cyclic tetra(amino)tetraborane published in @NatureComms ! Thanks to all contributors! https://t.co/5GP4DRd3Nd
#chemtwitter #11B #UniWue
nature.com
Nature Communications - While small carbocyclic rings have long been recognized as pivotal building blocks in chemistry, their all-boron counterparts have remained largely unexplored. Here, the...
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Exited to share that the first paper of my postdoc in @GroupAldridge is finally out in @angew_chem! In this work, we studied addition processes of different E-E bonds at tin(II) and got some really unique compounds! @JosefBoronski @A_Swarbrook
Breaking bonds at tin(II)! We've had a look at the spectrum of bond addition reactions, from reductive (Be-Be) to oxidative (Cl-Cl), and everything in between (B-B, B-H, H-H) @angew_chem @GroupAldridge @maxxdietz @A_Swarbrook
https://t.co/1oyTSXwmD9
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Corni's latest work on symmetrical and unsymmetrical cyclic diborenes is now published in @ChemicalScience! Many thanks to @kar_sourav, Andreas, @dario_duwe, and Rian! #chemtwitter #11B #UniWue
https://t.co/qNMvV13YVD
pubs.rsc.org
Cyclic diborenes are recognized for their diverse reactivity and properties arising partly due to their ring strain. However, progress in this field has been relatively slow due to the unavailability...
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Check out @LeonieWuest 's latest work on isolable 1,2,3-diazaborine alkali metal complexes, now out in @ChemicalScience! Many thanks to @wellnitz_tim and Kris! #chemtwitter #11B #UniWue
https://t.co/bvrJ0Tubmr
pubs.rsc.org
The standard procedure for the preparation of benzoid 1,2,3-diazaborines (DABs) is the condensation of 2-formylphenyl boronic acid with a hydrazine. The choice of hydrazine derivative irreversibly...
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Check out @wellnitz_tim´s recent work in cooperation with @hering_lab on the reactivity of Pnictaalumenes towards 1,3-Dipole Molecules, now published in @angew_chem! - The result of persistence and many late-night shifts! https://t.co/EQ6WWBQQfT
onlinelibrary.wiley.com
Pnictaalumenes with a Pn═Al multiple bonds undergo azide or diazoalkene insertions rather than [3+2] cycloadditions. This results in AlN2P heterocycles, which show a great structural variety depend...
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✨Shiny news!✨ Congratulations to the first authors, @LeonieWuest and @Johannes_Chb, on the publication of your 1,2,3-benzodiazaborine cooperation paper in @ChemicalScience. Well done! https://t.co/iLPuM4sVr8
pubs.rsc.org
1,2,3-Benzodiazaborines (DABs), isoelectronic to isoquinoline alkaloids, have attracted considerable interest due to their unique reactivity and promising potential applications, including but not...
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Check out Yannick's latest work on dicoordinate alkylborylene, now out in @angew_chem Thanks to @AruJayaram6 and Ivo! #chemtwitter #11B #UniWue
Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene (@LabBraunschweig): https://t.co/RJvvUjy5Dk (@angew_chem).
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Congratulations Dr Griffin! Many congrats to grad student @liampgriffin on defending his doctoral thesis today. Big thanks also to Meera Mehta and @LabBraunschweig for doing the viva! Some of Liam's recent work can be found here: https://t.co/k37a0J5g85
@OxICFM @OxfordChemistry
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Triple Bond Formed Between Boron and Carbon: The synthesis of a neutral boryne Check out @maxi_michel_’s latest work, now online in @NatureSynthesis
https://t.co/DEikqQbLGk Thanks to @kar_sourav, Lukas, Rian, and Bernd! #chemtwitter #11B #UniWue
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