Hye Won (Hanna) Moon
@hyewon__moon
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문혜원 | Assistant Prof at DGIST 🇰🇷 | formerly: Postdoc in @CornellaLab (MPIKOFO), PhD from the Radosevich group (@ChemistryMIT)
Daegu, South Korea
Joined September 2011
Excited to share our group's new paper. Thanks to all involved.
Air- and Water-Stable Sulfide Radical Cations Supported by Cyclic (Alkyl)(amino)carbenes | Journal of the American Chemical Society
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Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage Another piece of the puzzle of Bismuth reactivity @CornellaLab @hyewon__moon @MrIrieman @Nils_Not_
https://t.co/jTGGcHyLkq
pubs.acs.org
Herein, we describe a unique example of a low-valent monocoordinated Bi(I) complex acting as a Lewis base partner in a FLP activation reaction. The interplay between a bulky and rigid Bi(I) and the...
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Zwitterionic Heavier Pnictinidenes in Redox Catalysis (Oriol Planas and co-workers) #AngewandteVIP #openaccess 🔓
onlinelibrary.wiley.com
Zwitterionic pnictinidenes: A new class of zwitterionic heavier pnictogen species stabilized by bis(N-heterocyclic carbene)borate ligands is reported, enabling the isolation of Sb and Bi in multiple...
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🎉 Proud moment! Our Main Group team just published their 2nd paper in @JACS_Au! They uncovered how O₂ activation mechanisms differ across P, Sb, and Bi - pushing the boundaries of main group chemistry 🧪 Read more:
pubs.acs.org
Electronic structure–reactivity relationships are fundamental to advancing the redox chemistry of main-group elements. Herein, we investigate a series of planarized C2v pnictogen complexes (Pn = P,...
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🚨Out! Red-shifted activation and coupling of RAEs using NADH as bio-reductant. First steps towards integrating alkyl radical chemistry in biological settings. Huge effort by David and Uxía! @ciqususc @MetBioCat Thanks @OrgBiomolChem for the invitation! https://t.co/8CgJofsgNw
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We are looking for a new postdoc to join @LipshultzSBU to work on synthetic methods enabled by catalytic photochemistry of catalyst-substrate complexes! Please apply here by May 8: https://t.co/uaVppgQ5s3
#chempostdoc
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Join us for the MGC (IOS/Sage) webinar next week! I'll be presenting Pn redox chemistry that I worked on during my PhD and postdoc.
Main Group Chemistry (IOS / Sage) Webinar Thurs. 16 Jan. 2025
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Excited to share our work (@EunsungLee5) in collaboration with Prof. Tae-Lim Choi's group! Air-stable ruthenium catalysts with tethered CAAC ligands for REMP. A heartfelt thank you to the reviewers and editor for their invaluable advice!
pubs.acs.org
Ring expansion metathesis polymerization (REMP) has emerged as a potent strategy for obtaining cyclic polymers over the past two decades. The scope of monomers, however, remains limited due to the...
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Our manuscript “A trimetallic bismuth(I)-based allyl cation” is now online! Check it out: https://t.co/awsVRrplJq
@NatureChemistry Diving into the dark side of Inorg Chem was a pleasure with @CornellaLab @Nils_Not_ @MrIrieman F. Neese, M. Van Gastel, and L. Wagner!
nature.com
Nature Chemistry - Heavier analogues of unsaturated organic molecules are of interest because of their bonding situation and their potential use in synthesis. Now, a Bi(I)-based allyl cation, which...
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Direct Determination of a Giant Zero-Field Splitting of 5422 cm–1 in a Triplet Organobismuthinidene by Infrared Electron Paramagnetic Resonance | JACS @CornellaLab
#ZeroFieldSplitting #Organobismuthinidene #IR #Paramagentic #Resonance
pubs.acs.org
Stable monocoordinated organobismuthinidenes were only recently isolated and analyzed toward their chemical and electronic structure. Quantum chemical calculations on tBu-MSFluind-Bi(I) (2) predicted...
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Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi(I)/Bi(III) Redox Cycling (Josep Cornella and co-workers) @hyewon_moon @Nils_Not @MrIrieman @JenniferKuziola @CornellaLab #openaccess
onlinelibrary.wiley.com
The reaction between N,C,N-pincer bismuthinidenes and organic azides leads to isolation of elusive monomeric iminobismuthanes, which can be spectroscopically and crystallographically characterized....
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What happens when you mix carboxylic acids and pyridines? Acid-base reaction? You are only partially right. Check our latest article, isocyanates can greatly enhance the photochemical expansion of pyridines to 1,2-diazepines! @ILV_UMR8180 @XMoreau_ILV
https://t.co/JFP9HaLnNs
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https://t.co/nFFtNgguF9 Our paper on the synthesis of securingine B and its application into the development of a new photoswitch is out @Chem_CP. Congrats Sangbin and @kang_gyumin, and our collaborators, especially Prof. Dongki Yoon. @KAIST_Chem @kaistpr #totalsynthesis
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Interested in some more nice monomeric Bi structures 🔎? Then, have a look on newest article about iminobismuthanes ⬇️⬇️⬇️!
The third article of @CornellaLab Bi ACIE trilogy this week! Check out the structure of monomeric iminobismuthanes (work done w/ @Nils_Not_, @MrIrieman, and @JenniferKuziola): https://t.co/P1XYEyJ0Pn
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The third article of @CornellaLab Bi ACIE trilogy this week! Check out the structure of monomeric iminobismuthanes (work done w/ @Nils_Not_, @MrIrieman, and @JenniferKuziola): https://t.co/P1XYEyJ0Pn
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I'm excited to finally share my favorite project from my PhD journey at @CornellaLab (w/ @hyewon__moon , @MrIrieman , @Nils_Not_ , & @vabeland : the monomeric triarylbismuthine oxide💎- the missing piece of the pnictine oxide series 🧩! https://t.co/B17KflB42r
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Now out! Activation and C‒C Coupling of Aryl Iodides via Bismuth Photocatalysis. https://t.co/KKGUkCbrPW Check our last report from @CornellaLab, achieving the catalytic formation of C(sp2)-C(sp2) bonds with bismuth, using not only 1 but 2 photochemical steps!
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Toast to the bimetallic team in our group for our first TM-based chemistry published in @J_A_C_S We introduced a new platform for the mimicry of Cu-ZSM-5, highlighting the role of aluminum in hydrogen atom abstraction reactivity! Way to go!
pubs.acs.org
Bimetallic complexes have sparked interest across various chemical disciplines, driving advancements in research. Recent advancements in this field have shed light on complex reactions in metalloen...
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Really proud of this one! 😊 I got to lean into my training, expand my skill set and broaden my perspective! Thanks to everyone in @CornellaLab for useful discussions and moral support (proud to be on this team), collaborators @Nils_Not_ & @MrIrieman and @NSERC for funding!
Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center | Journal of the American Chemical Society @CornellaLab #SF6 #PhSF5 #Bismuth
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Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center | Journal of the American Chemical Society @CornellaLab #SF6 #PhSF5 #Bismuth
pubs.acs.org
In this work, we report the catalytic degradation of SF6 and PhSF5 using N,C,N pincer bismuthinidene complexes (1 and 5). Exposure of SF6 and PhSF5 to 1 results in the reduction of the S(VI) substr...
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