Davide Spinnato
@DavideSpinnato2
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Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage Another piece of the puzzle of Bismuth reactivity @CornellaLab @hyewon__moon @MrIrieman @Nils_Not_
https://t.co/jTGGcHyLkq
pubs.acs.org
Herein, we describe a unique example of a low-valent monocoordinated Bi(I) complex acting as a Lewis base partner in a FLP activation reaction. The interplay between a bulky and rigid Bi(I) and the...
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Al Ministero della Salute conoscevano tutte le misure da implementare per prevenire la diffusione del #westnile, eppure non hanno fatto niente. Questo è quello che il Ministro Schillaci ha sostanzialmente ammesso durante la sua informativa alla Commissione Sanità del Senato.
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I have never felt so shaken. Children are dying of hunger. Falling one after another, like petals of a dying flower. Under our watch. How do you sleep, Presidents, Foreign Ministers, political leaders, diplomats, civil servants - doing nothing to stop Israel’s starvation
The sheer intellectual collapse you have to experience to be faced with 122 international aid organisations telling you the same thing... ISRAEL IS STARVING GAZANS... only to decide they are ALL lying & that actually Benjamin Netanyahu, on trial for fraud, is telling the truth.
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Quando dissi qualche mese fa che Gaza era un test morale alludevo a questo. Aver lasciato che accadesse la carneficina in Palestina ha aperto la strada a nuove brutali violenze da parte di Israele. Adesso ci dicono anche che questo "lavoro sporco" lo fanno "per noi". #NotInMyName
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“Saviano va punito". “Saviano fa schifo". “Io domani esco con una palata di letame contro Saviano”. Quelli che leggete in alto sono alcuni dei messaggi che Giorgia Meloni e Guido Crosetto hanno riservato a Roberto Saviano. Insulti, odio, violenza verbale. Contro chi? Contro un
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«Sono entrato nel campo di sterminio di Birkenau col numero B 7456 stampato sul braccio sinistro. Prima di morire, mio padre mi disse “tieni duro, ce la devi fare”. Ho seguito le sue parole, ero uno scheletro». Il racconto e le lacrime di Sami Modiano. #Giornodellamemoria
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Our manuscript “A trimetallic bismuth(I)-based allyl cation” is now online! Check it out: https://t.co/awsVRrplJq
@NatureChemistry Diving into the dark side of Inorg Chem was a pleasure with @CornellaLab @Nils_Not_ @MrIrieman F. Neese, M. Van Gastel, and L. Wagner!
nature.com
Nature Chemistry - Heavier analogues of unsaturated organic molecules are of interest because of their bonding situation and their potential use in synthesis. Now, a Bi(I)-based allyl cation, which...
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Direct Determination of a Giant Zero-Field Splitting of 5422 cm–1 in a Triplet Organobismuthinidene by Infrared Electron Paramagnetic Resonance | JACS @CornellaLab
#ZeroFieldSplitting #Organobismuthinidene #IR #Paramagentic #Resonance
pubs.acs.org
Stable monocoordinated organobismuthinidenes were only recently isolated and analyzed toward their chemical and electronic structure. Quantum chemical calculations on tBu-MSFluind-Bi(I) (2) predicted...
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Week 1 in Vienna: done! ✅ And to celebrate it, our website is live—dive into the Mateos Group's research: https://t.co/iG03qgw15Z
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https://t.co/TsYAVZ8wty Pleased to share our latest work in @Nature. This paper wraps up our research at @ICIQchem , and I’m grateful for their incredible support! Looking forward to continuing the journey with the @MelchiorreGroup @Unibo !
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Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. @J_A_C_S
https://t.co/FLZoHqFXI2 with @ShengyangN & @DavideSpinnato2
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[W]+ with @DavideSpinnato2, @Nils_Not_, @MrIrieman, M. van Gastel, L. Wagner and F. Neese https://t.co/tKchkCqauL
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Pleased to finally share my PhD work - an enantioselective organocatalytic [1,2]-rearrangement of ammonium ylides. Check out the pre-print now https://t.co/apyCedoYna ; massive effort from all involved @ADS10_StAndrews, @ChemGreenhalgh, Kevin, the Oregon comp. team and others!
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