Cornellab
@CornellaLab
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Synthesis focused. Catalysis driven. At Max-Planck-Institut für Kohlenforschung
Mülheim an der Ruhr
Joined April 2017
Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage Another piece of the puzzle of Bismuth reactivity @CornellaLab @hyewon__moon @MrIrieman @Nils_Not_
https://t.co/jTGGcHyLkq
pubs.acs.org
Herein, we describe a unique example of a low-valent monocoordinated Bi(I) complex acting as a Lewis base partner in a FLP activation reaction. The interplay between a bulky and rigid Bi(I) and the...
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Our syntheses of harziane diterpenoids (including harziandione and harzianone) are now out in @J_A_C_S . This work highlights again the power of Baran reductive olefin coupling (BROC) in building sterically hindered C−C bonds: https://t.co/UlKI7hHPUc
pubs.acs.org
Harziane diterpenoids possess a highly caged 6/5/7/4 core framework and four contiguous stereocenters, including two quaternary ones, and present significant challenges to chemical synthesis. Herein,...
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Isolation and Characterization of an Organobismuth Dihydride | Journal of the American Chemical Society @CornellaLab
pubs.acs.org
We report the synthesis, isolation, and structural characterization of an elusive organobismuth(III) dihydride (Ar*–Bi(III)–H2, 1). The complex features a bulky and rigid tBu-MsFluind ligand that...
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Incredibly useful chemistry. Congrats! 🎆
Check out this new direct #CHfunctionalization method for fused azines at #ACScentralscience : broad, metal-free and proceeding with exclusive and predictable #regiocontrol! Executed in #parallelmode for its immediate application to #drugdiscovery! 💊 https://t.co/WQFXu9k4jQ
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Check out this new direct #CHfunctionalization method for fused azines at #ACScentralscience : broad, metal-free and proceeding with exclusive and predictable #regiocontrol! Executed in #parallelmode for its immediate application to #drugdiscovery! 💊 https://t.co/WQFXu9k4jQ
pubs.acs.org
Direct manipulation of C–H bonds enclosed in complex scaffolds persists today as an elusive disconnection when aiming for high and predictable site-selectivity. Its development toward the late-stage...
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So excited the team has made a nitrogen allotrope! Check it out here:
nature.com
Nature - The facile synthesis and spectroscopic identification of previously unreported hexanitrogen C2h-N6 is described, representing experimentally realized neutral molecular nitrogen allotropes...
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Congratulations Ignacio Cirac of @MPI_Quantum, newly inducted NAS international member! #NAS162 #NASmember #quantum #physics
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Congratulations Kyoko Nozaki of @UTokyo_News_en, newly inducted NAS international member! #NAS162 #NASmember #chemistry
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Congrats to Prof. Dale Boger (@BogerLab), who was awarded the 2025 Chemical Pioneer Award for his seminal work in natural product synthesis and molecular design. With 625+ papers and 300+ trainees, his research has shaped modern medicinal chemistry. More:
magazine.scripps.edu
Dale L. Boger, PhD, the Richard and Alice Cramer Professor in Chemistry at Scripps Research, has been awarded the 2025 Chemical Pioneer Award by the American Institute of Chemists (AIC).
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🌍 100 years of Fischer-Tropsch! A chemical process from Mülheim, now key to green fuels & the #EnergyTransition. Join the global scientific community May 5–7 to celebrate, discuss & shape the future. 🔗 https://t.co/4oRyKN3uyU
#FischerTropsch100
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"For quantifying reactive species in the gas-phase to solve fundamental problems in catalysis.“: Helmut Schwartz, Wolf Prize Laureate in Chemistry 2025, has made monumental contributions to catalysis by quantifying reactive species in the gas phase. Celebrate his groundbreaking
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Elevating top-tier chemistry research! Charlotte Gers-Panther, Frank Maaß, and Nathalie Weickgenannt introduce the unique concept of #AngewandteChemieNovit in their Editorial. Check it out: https://t.co/T0POBrKYIf
@GDCh_aktuell
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Catalytic hydrogenation and metal-catalyzed cross-coupling are among the most broadly utilized methods in small-molecule drug discovery and manufacture (1/3).
nature.com
Nature Chemistry - Transfer hydrogenation is challenging to apply to aryl halide reductive cross-couplings because of competing hydrogenolysis. Now aryl halide cross-couplings mediated by sodium...
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Postdoc position available in our group @ICIQchem, in collaboration with @AstraZeneca! Combine academic and industrial research in a unique opportunity. https://t.co/amy7g5OO5f
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🚨Calling medicinal chemists🚨: A Suzuki het-het coupling sometimes does not require complex ligands. An air stable Ni would do. Amazing work from @rsaeb2 Rakan Saeb and Byeongdo Roh. https://t.co/JpfG9dmLiz
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Red-Light-Active N,C,N-Pincer Bismuthinidene: Excited State Dynamics and Mechanism of Oxidative Addition into Aryl Iodides | Journal of the American Chemical Society @Totalsynth @CornellaLab
@mato_mauro @MrIrieman @GilSepulcre
@CadraLab
pubs.acs.org
Despite the progress made in the field of synthetic organic photocatalysis over the past decade, the use of higher wavelengths, especially those in the deep-red portion of the electromagnetic...
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A very cool Bismuth MLCT chromophore with red-light photocatalytic activity. Fantastic collaboration!
Deciphering the mechanism of oxidative addition of aryl iodides into a red-light active bismuthinidene. Incredible team: Alexios Stamoulis, @mato_mauro, Paolo Cleto-Bruzzese @MrIrieman, @GilSepulcre @CadraLab & Frank Neese. https://t.co/WpCGwvB73z
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Deciphering the mechanism of oxidative addition of aryl iodides into a red-light active bismuthinidene. Incredible team: Alexios Stamoulis, @mato_mauro, Paolo Cleto-Bruzzese @MrIrieman, @GilSepulcre @CadraLab & Frank Neese. https://t.co/WpCGwvB73z
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