Schulz Group
@SchulzGroup
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Molecular inorganic chemistry @unirostock since 2006. We ❤ phosphorus, nitrogen, biradical(oid)s, molecular switches and unusual molecules.
Joined March 2021
RT @angew_chem: @Ghadwal_Group reports the synthesis of a bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid with a stretched bridgehead Ge–….
onlinelibrary.wiley.com
The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characte...
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A Thorough Characterization of the Tellurocyanate Anion - Günther - Angewandte Chemie International Edition - Wiley Online Library
onlinelibrary.wiley.com
[K@crypt-222][TeCN] was synthesized from KCN, Te, and crypt-222 in acetone. We discuss fundamental properties of [TeCN]−: Single crystal X-ray diffraction, nuclear magnetic resonance (13C, 15N,...
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N6 coolest molecule ever. tried the synthesis myself 30 years ago but failed.
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Wir freuen uns sehr über das Benchtop-NMR-Gerät „Spinsolve 80“ von @magritek! Damit ergeben sich für uns neue, vielfältige Möglichkeiten, um Syntheseprodukte und -wege zu untersuchen! @unirostock 🇪🇺 #efre_mv #euinmyregion.
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We are looking for a Phd student to work in the field of synthesis (molecular switches, CO2 activation) within our research training group. Please feel free to contact me .
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RT @angew_chem: Visualization Analysis of Covalent and Noncovalent Interactions in Real Space (Tian Lu) #AngewandteReview • .
onlinelibrary.wiley.com
This article comprehensively reviews various methods that based on real space functions for visually studying covalent and noncovalent interactions. Methods such as NCI, IRI, IGM, IGMH, amIGM, ELF,...
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RT @angew_chem: Azobenzene-Oxindole Photochromic Dyads (Ben L. Feringa and co-workers) @FeringaLab #openaccess 🔓
onlinelibrary.wiley.com
A novel photochromic azobenzene-oxindole dyad is reported. The combination of the two switches promotes drastic molecular geometry changes and allows for precise NMR quantification. This enables the...
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RT @Petrov_chem: Together with @GroupMullerFU we elucidated the molecular structure of "naked" cyclo-P5- in the crystal! Special thanks to….
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RT @RJGilliard: Our manuscript on dicationic boron derivatives of Schlenk's and Thiele's hydrocarbon is now online @J_A_C_S! @PDabringhaus….
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When the little N meets the big Bi . Nitrogen-Based Ligands in the Coordination Sphere of Bismuth.
link.springer.com
The heavy bismuth, a metal, and the light nitrogen, a non-metal, both elements of the 15th group of the periodic table of the elements, do not occur in nature in a binary compound. In addition to...
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RT @J_A_C_S: NIR-Responsive Double Closed-Ring Isomer of a Diarylethene Fused Dimer Synthesized by Stepwise Photochemical and Oxidative Cyc….
pubs.acs.org
The double closed-ring isomer of a diarylethene fused dimer was synthesized by a combination of photochemical and oxidative cyclization reaction. The double closed-ring isomer of a diarylethene fused...
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RT @LLL_lab_SUSTech: Congrats to Xin-Feng, Rui, Walter and Chaopeng! We documented the isolation of keteniminyl anions [RC=C=NR]-, now feat….
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RT @DielmannGroup: One week from today we‘ll welcome the participants of this year‘s #EWPC21 in Innsbruck! Preparations are in full swing a….
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Well done, Karsten - 2years of hard lab work!. Reaction of NHOs with Bisphosphanes – Designing Diradicaloids, Zwitterions and Radicals - Lüdtke - Angewandte Chemie International Edition - Wiley Online Library
onlinelibrary.wiley.com
By linking N-heterocyclic olefins with a P-substituted indenyl heterocycle, it was possible to synthesize a very exciting new heterocyclic substance class that is both zwitterionic and diradical....
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Dipnictogen Radical Chemistry: A Dithorium-Supported Distibene Radical Trianion | Journal of the American Chemical Society
pubs.acs.org
Although two examples of σ-bonded trans-bent [RSbSbR]•– (R = bulky organo- or Ga-groups) that formally contain the Sb2•3– radical trianion moiety are known in p-block chemistry, d- or f-element...
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RT @ChemicalScience: 📢 NEW #ChemSciCovers. 'Dithienoarsinines: stable and planar π-extended arsabenzenes' by Hiroaki Imoto et al. 🔗 https….
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RT @RiedelLab: Now anyone is able to synthesise it😉 Just out in @angew_chem. Easily accessible route for fluorinated trityl cations, which….
onlinelibrary.wiley.com
Herein, we present the easy-to-access synthesis of the perfluorotrityl cation and the further functionalization of its para-fluorine atoms via halodefluorination using trimethylsilyl halides TMSX...
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RT @m_malischewski: A great start into 2025! Results from @berg_willi master thesis have been published in @J_A_C_S : Read about the isola….
pubs.acs.org
Herein, we report the solvent-dependent reactivity of Fe(CO)5 toward AsF5 in either anhydrous HF or liquid SO2. The reaction of Fe(CO)5 with the superacid HF/AsF5 leads to the protonation of the iron...
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