Moritz Malischewski
@m_malischewski
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Junior Research Group Leader, Inorganic Chemistry, Freie Universität Berlin
Berlin, Germany
Joined December 2020
New paper out in ACS Omega: We compare the σ-donor and π-acceptor properties of fluorinated isocyanide complexes with their non-fluorinated analogues using the EDA-NOCV method. 🔗 https://t.co/Tlu9dOZ3iO
#InorganicChemistry #Organometallics #ComputationalChemistry
pubs.acs.org
While perfluorinated isocyanide ligands such as CNCF3 and CNC6F5 have been known for decades, their use by organometallic chemists has been limited primarily due to the challenges associated with...
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Great collaboration, Malte!
New paper out in ACS Omega: We compare the σ-donor and π-acceptor properties of fluorinated isocyanide complexes with their non-fluorinated analogues using the EDA-NOCV method. 🔗 https://t.co/Tlu9dOZ3iO
#InorganicChemistry #Organometallics #ComputationalChemistry
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Now published in Chemical Science: https://t.co/EvA0XujMuC Even when incorporated into ferrocene or ruthenocene, the perfluorinated Cp* ligand is susceptible to substitution.
pubs.rsc.org
The electron-deficient ferrocene [Fe(C5H5)(C5(CF3)5)] is complemented by the synthesis and full characterisation of the analogous bench-stable ruthenocene [Ru(C5H5)(C5(CF3)5)]. These complexes have...
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Our new article in Angewandte Chemie is about pushing the limits of organometallic redox chemistry https://t.co/c1uVBqKC9H
onlinelibrary.wiley.com
The synthesis and full characterization of the electron deficient ferrocene [Fe(C5H5)(C5(CF3)5)] and its ferrocenium salt is reported. An extreme redox potential of E1/2 = 1.35 V (versus Fc/Fc+)...
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A great start into 2025! Results from @berg_willi master thesis have been published in @J_A_C_S : Read about the isolation of [FeH(CO)5]+ and [Fe2(CO)10]2+ Journal of the American Chemical Society
pubs.acs.org
Herein, we report the solvent-dependent reactivity of Fe(CO)5 toward AsF5 in either anhydrous HF or liquid SO2. The reaction of Fe(CO)5 with the superacid HF/AsF5 leads to the protonation of the iron...
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The first structure with bismuth acting as a halogen bond acceptor has been reported in @J_A_C_S. The unstable adduct CSD entry XUCFAG displays Bi…I contacts below the sum of the van der Waals radii and elongated C-I bonds. 🔗 https://t.co/Fy8qpli3pH
#FeaturedStructureFriday
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Thanks for your visit and your great research talk.
Yesterday I had the pleasure to present a research seminar at @FU_Berlin & visit the institute of inorganic chemistry. So much fascinating chemistry ongoing there, I am impressed! Many thanks @m_malischewski for the kind invitation!
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Crystallographic Evidence for Bi(I) as the Heaviest Halogen Bond Acceptor | Journal of the American Chemical Society @UIBuniversitat @tonifrontera3 @m_malischewski @FU_Berlin #Crystallography #Bi #HalogenBond #Acceptor
pubs.acs.org
Complexation of the green bismuthinidene (RBi) with two equivalents of a highly fluorinated aryl iodide at low temperature allows the crystallographic identification of an unstable red species that...
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I am very proud of our great collaborative work: record-breaking halogen bonding with very heavy main group elements
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Some time ago, my colleague @GDreyhsig and I had the special opportunity to welcome a special guest at @FU_Berlin to get to know another world of chemistry: the entertainment (but also teaching) industry! https://t.co/fdmc698ko7
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On Friday 11.10.24 from 10:00 to 16:00 the groups of our inorganic chemistry institute at FU Berlin will present their research. Following the research talks a BBQ is planned in the late afternoon.
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The tweet is a little late but: I am very proud and grateful to have been awarded the Wöhler-BASF Young Talent Award. Many thanks to everyone who contributed to this success.
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Substitution Lability of the Perfluorinated Cp* Ligand in [Rh(COD)(C5(CF3)5)] Towards Triphenylpnictogens EPh3 (E=N, P, As, Sb, Bi) (Moritz Malischewski and co-workers) @m_malischewski
chemistry-europe.onlinelibrary.wiley.com
In this paper we present the structural diversity of products formed upon substitution of the labile perfluorinated Cp* ligand [C5(CF3)5]− in [Rh(COD)(C5(CF3)5)] (COD=1,5-cyclooctadiene) by triphen...
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📣Next call for @fubcp RISING STAR 2-year #Postdoc #fellowships
#biology #biochemistry #chemistry #pharmacy For early-career researchers who have completed their doctorates within the last 4 years - preferably from abroad Deadline: May 31, 2024 https://t.co/R2JgrKzKFE
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It is a great honour for me to have been awarded one of this year's ADUC prizes. Thank you very much!
Opening of the CDT 2024 in Aachen, Germany: Award ceremony by Hans-Dieter Arndt @UniJena, ADUC Chair. Left: Jola Pospech @likat_rostock, right: Moritz Malischewski @FU_Berlin. Congrats! #GDChAwards #GDChPreise @GDCh_aktuell
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Pushing Boundaries of Oxidation States with Fe: "Synthesis and characterization of an iron(VII) nitrido complex" 😲😲😱😱🤯 Happy to have been part of this massive work with K. Meyer @SAVJannuzzi @mpicec_press @m_malischewski Finally out @NatureChemistry
https://t.co/SNjqOgqd5J
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What’s the highest oxidation state for an Fe molecular complex? It’s now 7️⃣! Check it out @NatureChemistry at https://t.co/25lLsLs3hh. XAS and Mössbauer by us at @mpicec_press, brilliant calculations by @MunzDominik and gorgeous syntheses by K. Meyer @UniFAU and @m_malischewski.
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Structural characterization and reactivity of a room-temperature-stable, antiaromatic cyclopentadienyl cation salt
nature.com
Nature Chemistry - The synthesis, structure and reactivity of room-temperature-stable [Cp(C6F5)5]+[Sb3F16]− is presented. Coordination of the cyclopentadienyl cation by [Sb3F16]− or...
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Coordination of Tetracyanoquinodimethane-Derivatives with Tris(pentafluorophenyl)borane Provides Stronger p-Dopants with Enhanced Stability | ACS Applied Materials & Interfaces
pubs.acs.org
Strong molecular dopants for organic semiconductors that are stable against diffusion are in demand, enhancing the performance of organic optoelectronic devices. The conventionally used p-dopants...
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