Ghadwal Group
@Ghadwal_Group
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Molecular Inorganic Chemistry and Catalysis Group @unibielefeld 📌Open-Shell Main-Group and Organometallic Chemistry enthusiastic C-Donors📌
Bielefeld, Deutschland
Joined February 2018
Annulated 1,4-Disilabenzene-1,4-diide and Dihydrogen Splitting @J_A_C_S kudos @Falk_Eb @Ghadwal_Group @unibielefeld @aromaticity_eu #silicon #aromaticity #hydrogen #main_group thanks @dfg_public.
pubs.acs.org
The isolation of silicon analogues of phenyl anions such as (C6H5)− and (C6H4)2– is challenging owing to their extremely high reactivity associated with their silylene character and weak C–Si...
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RT @ChemEurJ: #CoverFeature Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4-diides: Interplay Between Diradical Cha….
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RT @isra_group: Nice cover designed by @DanielPinardo to illustrate our work in @ChemEurJ on Understanding Small Molecule Activation Promo….
chemistry-europe.onlinelibrary.wiley.com
The Cover Feature shows that the increased diradical character in annulated heavier Group 14 benzene-1,4-diides is translated into an enhanced reactivity towards small-molecule activation. More...
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Absolutely beautiful cover by Dani and Isra! @isra_group @ChemEurope .Thanks for having me on board - @Ghadwal_Group.
chemistry-europe.onlinelibrary.wiley.com
The Cover Feature shows that the increased diradical character in annulated heavier Group 14 benzene-1,4-diides is translated into an enhanced reactivity towards small-molecule activation. More...
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RT @wipf_group: Cool germanium BCB- and it’s a nonclassical diradical ⚡️⚡️⚡️ Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid - Ebeler - A….
onlinelibrary.wiley.com
The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characte...
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In case you are interested in the German version: @Ghadwal_Group.
onlinelibrary.wiley.com
Die Bicyclo[1.1.0]tetragerman-2,4-diid-Diradikaloidverbindung [(ADC)2Ge4], die durch eine gestreckte Brückenkopf-Ge–Ge-Bindung gekennzeichnet ist, wurde als venezianroten kristallinen Feststoff...
Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: #maingroup #diradicals thanks to @dfg_public
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Thank you, @angew_chem, for providing a platform to showcase our work.
@Ghadwal_Group reports the synthesis of a bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid with a stretched bridgehead Ge–Ge bond as a Venetian red crystalline solid showcasing its electronic structure & reactivity #openaccess 🔓
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Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: #maingroup #diradicals thanks to @dfg_public
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RT @szczepanikgroup: Benzene, PAHs, macrocycles, nanorings, etc. We thought we understood aromaticity. BDF challenges what we see, what we….
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RT @isra_group: Check out our work just accepted in @ChemEurJ on Understanding Small Molecule Activation by Heavier Benzene 1,4‐diides: I….
chemistry-europe.onlinelibrary.wiley.com
The intricate relationship between diradical character, aromaticity, and reactivity in annulated heavier Group 14 benzene-1,4-diides (see picture) has been investigated through Density Functional...
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RT @angew_chem: Cyclic pnictogen-radical cations, valence-isoelectronic to the elusive aryl radical anions of Birch reductions, have been s….
onlinelibrary.wiley.com
One-electron (1e-) oxidations of the base-stabilized cyclic bis-pnictinidene compounds 1-E afford the 7π-electron C4E2-ring-containing radical cations [2-E]●+, which are valence isoelectronic to the...
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Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions—just published in @angew_chem Congratulations to Henric and all @Ghadwal_Group @bruin_bas Thanks @dfg_public .
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Paneth’s mirrors and the isolation of methyl radicals:
chemistryworld.com
Laying the groundwork for the study of combustion and photochemical reactions
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RT @angew_chem: Lithium Anionic Dicarbenes or Acetylides: What is in the Name? (Rajendra S. Ghadwal and co-workers) @Ghadwal_Group #Angewan….
onlinelibrary.wiley.com
The two-fold deprotonation of the C2-arylated 1,3-imidazolium salts with nBuLi affords the so-called lithium anionic dicarbenes Li(ADC). X-Ray diffraction studies reveal that Li(ADC) exist as...
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Here is the German version, in case: .
onlinelibrary.wiley.com
Die zweifache Deprotonierung der C2-arylierten 1,3-Imidazoliumsalze mit nBuLi führt zu den sogenannten anionischen Lithiumdicarbenen Li(ADC). Röntgenbeugungsuntersuchungen zeigen, dass Li(ADC) als...
The final proofed version is now online and has earned VIP status. Thanks to the reviewers for ranking this work #outstanding— top 5%! and providing constructive feedback. Thanks @angew_chem and @dfg_public .@Ghadwal_Group @ArneMrsl.
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The final proofed version is now online and has earned VIP status. Thanks to the reviewers for ranking this work #outstanding— top 5%! and providing constructive feedback. Thanks @angew_chem and @dfg_public .@Ghadwal_Group @ArneMrsl.
Lithium Anionic Dicarbenes or Acetylides: What is in the Name? (Rajendra S. Ghadwal and co-workers) @Ghadwal_Group #AngewandteVIP #openaccess 🔓
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Congratulations 🙌 and all the best for you and your future plans 💪💪💪.
Huge thanks to my mentors Prof Nagendran @SNagendranGroup, Prof Ghadwal @Ghadwal_Group, and Prof Schulz @unidue for their continuous support and guidance throughout this journey. I also would like to thank all my collaboraters for their support.
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RT @ChemEurope: #EurJIC Heavier Benzene-1,4-diides: Merging Aromatics and Metallylenes (Rajendra S. Ghadwal) @Ghadwal_Group #openaccess 🔓 h….
chemistry-europe.onlinelibrary.wiley.com
A conceptually new type of Group 14 compounds [(ADC)E]2 based on anionic dicarbene (ADC) scaffolds have been reviewed. The Group 14 elements in the planar C4E2 ring of [(ADC)E]2 are formally in +1...
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This work is dedicated to Professor Robert Mulvey on the occasion of his 65th birthday (.
Delighted to share the first original research article of 2025 by @Ghadwal_Group . in @angew_chem Lithium Anionic Dicarbenes or Acetylides: What is in the Name? congrats @ArneMrsl thanks to @dfg_public .👉
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Delighted to share the first original research article of 2025 by @Ghadwal_Group . in @angew_chem Lithium Anionic Dicarbenes or Acetylides: What is in the Name? congrats @ArneMrsl thanks to @dfg_public .👉
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Thanks, Ajay, group members @MainTvm @Chemie_iisertvm and Prof. Murthy @tvmiiser .That was a BLAST, well-organized, and engaging conference #ICMGSC2025 I Thoroughly enjoyed the exciting science and interactions with highly talented students. Superb infrastructure! 🙏🫶👌.
ICMGSC 2025: With the departure of the last guest on @tvmiiser campus, @Ghadwal_Group @unibielefeld, the second edition of ICMGSC comes to an end! .@RoySocChem @DaltonTrans
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