LLLiu Group
@LLL_lab_SUSTech
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The LLL group @SUSTechSZ. Main group chemistry. Views by Leo. We've migrated over to @llliugroup.bsky.social
Shenzhen, China
Joined October 2013
You are very welcome, Isra. Your presence and the discussions were incredibly valuable.
Super grateful to @LLL_lab_SUSTech for inviting me to learn more about your wonderful chemistry and the chemistry at SUSTech-Shenzhen
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Welcome Gavin! Feel free to drop by anytime—we look forward to more great interactions! 😊
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Crystalline Silagermenides as Powerful Synthons: Unraveling π-Bonding and Lone Pair Effects in the Multiple Bonds of Heavier Main Group Analogs of the Vinyl Anion (Liu Leo Liu and co-workers) @LLL_lab_SUSTech #AngewandteVIP •
onlinelibrary.wiley.com
Acyclic silagermenides are synthesized through a straightforward desilylation process. Their electronic properties are explored using DFT calculations, revealing a high-lying and polarized Si─Ge π...
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We are honored!
🌟Congrats to the 11th CCS-RSC Young Chemists Award Winners 🌟 Liu Liu - Main-group element breakthroughs, Dawen Niu - Game-changing glycosylation, Yan Qiao - Artificial cell frontiers &, Yuen Wu - Single-atom catalysis pioneer (in Chinese) 👉 https://t.co/xDxYvZ0XGL
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Glad to share my lastest work with @GoicoecheaGroup in @J_A_C_S .We reported a metathesis reaction between P(III)=O and P(V)=C, generating P(III)=C and P(V)=O, replacing carbonyl compounds in Wittig-raction with a phosphinidene oxide! https://t.co/8EtwzvevC9
pubs.acs.org
The reactivity of an unsupported phosphinidene oxide, BnArNP═O (Bn = benzyl; Ar = bulky aryl group), as the electrophilic partner in Wittig reactions with ylides is described. Reactions with methyl...
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Talented PI with a big start up package! Come to join LOH lab.
YKLab website just launched! 😊 Pls check it out! https://t.co/cNGpNlULuO
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happy to share our group's first submission/publication in Nature Communications on the isolation of a carbene-supported triphosphorus anion. We had an excellent peer review experience!
nature.com
Nature Communications - The stabilization of reactive anionic main group species utilizing carbenes constitutes a burgeoning and scarcely explored field. Herein, the authors report the synthesis of...
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Congrats to Xin-Feng, Rui, Walter and Chaopeng! We documented the isolation of keteniminyl anions [RC=C=NR]-, now featured in @Chem_CP!
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Heavier Analogs of Dioxiranes and Trioxetanes: Aluminadichalcogeniranes and aluminatrichalcogenetanes synthesized (work published in @angew_chem) https://t.co/TR3bw4Rg4t
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Second one online @ Acc. Chem. Res. in 2025. We summarize our journey with carbyne anion and related low-valent carbon chemistry.
pubs.acs.org
ConspectusThe advancement of synthetic methodologies is fundamentally driven by a deeper understanding of the structure–reactivity relationships of reactive key intermediates. Carbyne anions are...
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Thanks for highlighting our work!
Crystalline Mesoionic Diazasilole Synthesized: 1,4,2-Diazasilole containing a low-valent silicon atom displays characteristics of both a mesoionic silylene and a silylone (work published in @angew_chem) https://t.co/IWMFNYpV4D
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Thrilled to share our latest research on mesoionic silylene chemistry, now accepted in @angew_chem. Immense gratitude to the editors and reviewers for their insights. Congratulations to Xiaofang, Hongyu, and Walter on this achievement!
onlinelibrary.wiley.com
We report the isolation of a mesoionic diazasilole featuring a low-valent silicon center that exhibits properties characteristic of both mesoionic silylene and silylone. Preliminary reactivity...
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Synthesis of the Bulky Phosphanide [P(SiiPr3)2]− and Its Stabilization of Low-Coordinate Group 12 Complexes | Inorganic Chemistry https://t.co/Vee32lk7xO Kays and co-workers @InorgChem #phosphanide #bulky #Group12 #PMP #DFT #NMR
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New from Liu Leo Liu and co. at @SUSTechSZ '(Phosphino)(stannyl)carbene' @LLL_lab_SUSTech
https://t.co/nb2Z8dwS2D
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Explore the advantages of bulky cyclic phosphino groups over noncyclic ones in our latest study! now @ChemCommun Emerging Investigators 2024 #ChemComm60
pubs.rsc.org
The synthesis of a (phosphino)(stannyl)carbene is documented. The combination of phosphino and stannyl substituents imparts a highly ambiphilic nature to this carbene, enabling reactions with...
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Selective Hydroboration of C−C Single Bonds without Transition-metal Catalysis (@LLL_lab_SUSTech and Lipeng Wu): https://t.co/EzRYWtDjC9 (@angew_chem).
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