Dobrovetsky Group
@DobrovetskyG
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Our feature article in @ChemCommun’s #2025PioneeringInvestigators special issue on structurally constrained, cationic P(III) species is now online! It highlights a lot of our work in the field. Congrats to @Deependrabawari & @DoniaToami99!.
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RT @mifridm: In this preprint, we use fluorescent probes derived from all three clinically used polyene antifungals to reveal distinct loca….
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RT @The_Ye_Lab: Thrilled to share our first paper in Organometallics! @Orgmet_ACS Flash Communication: An Inorganic Version of Alkyne–Azid….
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RT @J_A_C_S: Isolation and Characterization of an Organobismuth Dihydride | Journal of the American Chemical Society @CornellaLab
https://t….
pubs.acs.org
We report the synthesis, isolation, and structural characterization of an elusive organobismuth(III) dihydride (Ar*–Bi(III)–H2, 1). The complex features a bulky and rigid tBu-MsFluind ligand that...
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RT @isra_group: Grateful for being part of this work with @DrFelixKraemer and R. Mulvey just published in @ChemEurJ as VIP article on Crown….
chemistry-europe.onlinelibrary.wiley.com
Crowned! Herein we describe a complete series of crown ether coordinated alkali metal phosphides from lithium to cesium, including solid state structures, detailed investigations in solution and...
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Officially promoted to full professor! I'm deeply grateful to all current and former lab members for their hard and creative work, and to my colleagues and mentors for their support over the years! 🙏🙏🙏.
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RT @AhmadMasarwa2: Our latest publication on the 'Photocatalytic Decarboxylative Functionalization of Bioactive, Naturally Occurring, and F….
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RT @kclenart_: Do you like radicals and FLPs and funky small molecule activations? Then the Caputo groups newest paper is the paper for you….
pubs.acs.org
Frustrated Lewis pairs (FLPs) have revolutionized main-group chemistry by enabling reactivity traditionally associated with transition metals. However, existing FLP systems are predominantly restri...
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RT @J_A_C_S: Hydrogen Activation by a σσ*-Carbene Through Quantum Tunneling | Journal of the American Chemical Society @HHU_de @uni_tue htt….
pubs.acs.org
The electronic structure of carbenes arises from the occupation of a σ and a π frontier orbital. While parent methylene possesses a triplet ground state (σ1π1), substituents are capable of stabiliz...
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RT @JensBeckmann16: Check out Fabio's next paper on the Nature of the Heavy Formal Double Bonds As=Ch, Sb=Ch and Bi=Ch (Ch = S, Se, Te) in….
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RT @organomimetic: My undergraduate advisor, Fred Hawthorne, once wrote, “One cannot fail to love borane chemistry since it recaptures the….
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RT @ChemJChu: Our work on the room-temperature ring-opening of benzene is now published in @J_A_C_S ! Great teamwork and thanks for the kin….
pubs.acs.org
Cleaving a benzene ring under mild conditions requires disrupting its aromaticity, which is a significant challenge in modern chemistry. Although the generation of cyclic products from cleaving...
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RT @chitnislab: Latest work from our group is a collab to extend hydro/halo metallation involving Sb and Bi to organometallics to make Fe/S….
pubs.rsc.org
Diaminostibines ({Sb}–H) add across the iron–carbon bond of a tucked-in iron diphosphine complex, resulting in hydrostibinated iron hydride [{Cp*-SbR2}Fe–H] complexes. The scope was broadened to...
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RT @haj19932469: Rikuro’s latest paper is now published in Angew. Chem. Int. Ed.! "Introducing Steric Bulk into Silylboranes: Enhanced Benc….
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RT @organomimetic: New preprint alert! Our latest work delves into the exploration of forging Boron-Tetrel bonds in carboranes. If you're i….
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Wow, cool.
So excited the team has made a nitrogen allotrope! Check it out here:
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RT @RJGilliard: Our manuscript on unlocking the ambiphilicity of boryl anions is now published in @J_A_C_S (! Chong….
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Very interesting and thorough study of the three structurally constrained pnictogen centers (P, Sb, and Bi) in a redox-active ligand. Congrats to the team!!.
🎉 Proud moment! Our Main Group team just published their 2nd paper in @JACS_Au! They uncovered how O₂ activation mechanisms differ across P, Sb, and Bi - pushing the boundaries of main group chemistry 🧪.Read more:
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RT @harder_research: LOW-VALENT Si, Ge, Sn, Pb: HOW LOW CAN WE GO???.Hydrocarbon-soluble Mg(0) reduces Si all the way to Si(4-). Unfortuna….
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RT @RJGilliard: Our (@gilliardgroup, @ccclabmit) manuscript on the generation of transient, sterically unhindered multiply bonded boron spe….
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RT @RJGilliard: Our manuscript on the first diboron-incorporated indenofluorenes is online in @J_A_C_S! Eric and coworkers report pentacycl….
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