Jens Beckmann
@JensBeckmann16
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Beckmann lab @ Universität Bremen Inorganic and organometallic chemistry of the p-block and late d-block elements
Bremen, Germany
Joined June 2021
RT @J_A_C_S: Isolation and Characterization of an Organobismuth Dihydride | Journal of the American Chemical Society @CornellaLab
https://t….
pubs.acs.org
We report the synthesis, isolation, and structural characterization of an elusive organobismuth(III) dihydride (Ar*–Bi(III)–H2, 1). The complex features a bulky and rigid tBu-MsFluind ligand that...
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RT @ChemEurJ: Crown Ether Supported Alkali Metal Phosphides: Synthesis, Structures and Bonding (Robert E. Mulvey and co-workers @StrathChem….
chemistry-europe.onlinelibrary.wiley.com
Crowned! Herein we describe a complete series of crown ether coordinated alkali metal phosphides from lithium to cesium, including solid state structures, detailed investigations in solution and...
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RT @Pine_Research: I'm very excited to make this BIG announcement 📢! Next month (September 2025) I will be offering a FREE 4-part webinar s….
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RT @GroupAldridge: The first of a couple of papers just coming out. Reversible alkyne functionalization at tin!.Aidan & Lewis’s study of….
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RT @McKenzie_SDU: Proposals for symposia for the next International Conference on Coordination Chemistry June 2026 can be submitted at http….
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RT @CoburgerPeter: Our latest publication reports the successful isolation of π-stabilized tetryliumylidenes [E–X]+ starting from pyramidan….
chemistry-europe.onlinelibrary.wiley.com
A series of cationic main-group complexes was obtained using the neutral, zwitterionic ligand IDP. The Lewis acidity of these complexes is explored by catalytic hydrophosphinations and halide...
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RT @ChemistryEur: Small Molecule Activation by Metallylenes and their Follow-Up Reactions by Trevor A. Hamlin and co-workers (@TrevorAHamli….
chemistry-europe.onlinelibrary.wiley.com
Metallylenes offer a promising, tunable platform for small molecule activation, combining transition metal-like reactivity with earth abundance. Ligand modifications and computational insights have...
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Check out Fabio's next paper on the Nature of the Heavy Formal Double Bonds As=Ch, Sb=Ch and Bi=Ch (Ch = S, Se, Te) in NCN-Pincer Supported Arsinidene, Stibinidene and Bismuthinidene Chalcogenides - now published in Chemical Science
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RT @YuyangDong: Check out our latest publication on Co nitrenoids, now out in JACS!.
pubs.acs.org
The bonding structures of cobalt nitrenoid complexes are fundamental to their reactivity across various transformations. However, unraveling the electronic configuration of these highly covalent Co–N...
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Next great paper by Martin (the machine) Hejda: Redox cycling at tellurium: Selective and multiple activation of Si–H bonds in common organosilanes and SiH4 - Hejda - Chemistry – A European Journal - Wiley Online Library
chemistry-europe.onlinelibrary.wiley.com
The tellurenyl triflate [2-(tBuNCH)C6H4Te][OTf] effectively activates the Si─H bonds of Et3SiH, Ph4–nSiHn (n = 1–3), SiH4, and complex H-siloxanes and catalytically converts them in the presence of...
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RT @J_A_C_S: Going to Extreme Lengths: Bicyclic Diborane(6) Anions and the Limits of Boron–Boron σ Bonding | Journal of the American Chemic….
pubs.acs.org
The reaction of (naphthalen-1,8-diyl)dilithium (NapLi2) with difluoro(mesityl)borane (MesBF2) in Et2O yielded a new 1,5-diborocine, 1, representing a straightforward route to this rare class of...
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RT @RiedelLab: Just out in @JACS_Au. Our new Aluminum-Based Lewis Superacid using a more bulky ligand -OTeF3PhF2. The corresponding WCA als….
pubs.acs.org
Lewis acids and their related weakly coordinating anions (WCAs) are central species in chemistry, and tuning their properties toward different purposes is still a challenging field of research. In...
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RT @bhkenlo: Experimental Evaluation of the Hydricity of Hydrosilanes | Inorganic Chemistry Sévery, Cantat, and co-….
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RT @algarciaromero: Excited to share our latest publication with the @GoicoecheaGroup in @angew_chem. In this work we explore the activati….
onlinelibrary.wiley.com
The stepwise insertion of acetylene into the E═E bonds of digallenes and diindenes is reported. This leads to the selective formation of four- and six-membered rings with 2π E2C2 and 4π E2C4 cores....
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RT @bhkenlo: Synthesis, Structure, and Property of Tris(biphenyldiyl)yttrium(III) Tris(binaphthyldiyl)yttrium(III) and Tris(binaphthyldiyl)….
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RT @J_A_C_S: Electron Sextets as Optically Addressable Molecular Qubits: Triplet Carbenes | Journal of the American Chemical Society @North….
pubs.acs.org
There is a growing demand in quantum information science and sensing for electron spin purification and readout via a spin-optical interface. This technique, known as optically detected magnetic...
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RT @MartinGroupBU: Our review on fluorenyl cations with @DuttonChemistry is now online in @ChemEurJ. Congrats to Kanika, Sameera, Ayesha, a….
chemistry-europe.onlinelibrary.wiley.com
This review covers the history of fluorenyl cations from Deno's first report in 1954 on the parent fluorenyl cation to the present. The parent cation and most derivatives have only been observed as...
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