Jett Janetzki
@jjanet97
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Australian postdoctoral research fellow in LAMM at the Uni. of Florence 🇮🇹 | Boskovic group alumnus l 🧲 ⚗️💎🏳️🌈
Joined May 2018
Excited to share another paper from my PhD - out in Chemical Science! .We report the first example of thermally- and light-induced valence tautomerism in an iron complex that occurs with a spin-state change. 💎🧲⚗️.
pubs.rsc.org
The switching phenomena of spin crossover (SCO) and valence tautomerism (VT) are respectively dominated by iron(ii) and cobalt-dioxolene systems. To explore new possibilities for SCO or VT, the...
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RT @GemGransbury: Really proud to share that our work on a Dysprosium compound with hysteresis at 100 K has been published in @Nature Lead….
nature.com
Nature - A dysprosium amide–alkene complex shows soft magnetic hysteresis loops up to 100 kelvin, arising from the high charge density of the amide ligands and the structural role of...
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RT @whoisBMH: Jack, Aaron, and Maya present an online angular overlap calculator, which can calculate d-orbital splitting for any geometry.….
pubs.acs.org
The study of coordination complexes in general and inorganic chemistry courses is facilitated by theoretical frameworks such as crystal field theory (CFT) and ligand field theory (LFT). The angular...
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RT @AleLunghi: Optical control of spin states in magnetic molecules:. A few thoughts on a rapidly evolving and very promising research topi….
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RT @kasperspedersen: 👋 We are excited to share an open PhD position in 4f/5f chemistry, with a focus on switchable materials, at the Techni….
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RT @ChemistryWorld: The discovery could allow researchers to fine-tune actinide bonding, potentially having huge implications for the entir….
chemistryworld.com
Modelling reveals that control of mysterious phi bonds could change behaviour of f-block elements
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RT @SchelterGroup: We discovered an in crystallo organometallic isomerization that shows 4f-orbitals can (uniquely) promote chemical react….
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RT @Johnseedo: Years in the making – 3-centre-1-electron trithorium metal-metal bonding. Out now in @NatureChemistry !. .
nature.com
Nature Chemistry - Superatoms are metal clusters that collectively behave like an atom, but they usually require metal–metal bonding and thus they are based on main group or transition...
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RT @J_A_C_S: s-Block Metal-Lanthanide Bonding: Direct Comparison of Mg–Yb and Mg–Ca Complexes | Journal of the American Chemical Society @V….
pubs.acs.org
Despite considerable progress in understanding the fundamental aspects of metal–metal bonding, lanthanide-metal bonding is limited to interactions between lanthanide (Ln) metals and electron-rich p-...
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RT @acboggiano: Excited to share the final version of Pr5+, now out in Nature Chemistry! Many thanks to co-authors, this was a huge lift fr….
nature.com
Nature Chemistry - The most common oxidation state for lanthanide elements is +3, and, beyond cerium, examples of these elements exhibiting higher oxidation states remain scarce. Now, a molecular...
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RT @ColetteBoskovic: From Georgie's Masters research @ChemistryUoM featuring #RedoxActiveLigands #Electrochemistry #XraySpectroscopy #FBlo….
pubs.acs.org
Molecular cerium complexes are of interest due to their remarkable redox and photophysical properties. We have investigated the ligand tunability of the electronic structure and properties of...
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RT @bhkenlo: Tuning the Electronic Properties of Tetravalent Cerium Complexes via Ligand Derivatization | Inorganic Chemistry https://t.co/….
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RT @J_A_C_S: η6-Benzene Tetra-Anion Complexes of Early and Late Rare-Earth Metals | Journal of the American Chemical Society .
pubs.acs.org
A novel synthetic route to the triple-decker benzene tetra-anion complexes [(η5-C5iPr5)M(μ:η6:η6-C6H6)M(η5-C5iPr5)] is reported for a range of early and late rare-earth elements, i.e., M = Y, La, Sm,...
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Thanks to the large team that made this possible - @ColetteBoskovic , @mjgians and Dominic Brown for optical measurements, @LabWeber and Florian Daumann for Mössbauer, Alyona Starikova for calculations, and Haseena Ismal, Robert Gable, Moya Hay, Roger Muldur for support.
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RT @tajchem98: Amazing feat for the f-element community! Berkelocene, the heaviest sandwich complex of the Periodic Table, unlocked. Many c….
science.org
Interest in actinide–carbon bonds has persisted since actinide organometallics were first investigated for applications in isotope separation during the Manhattan Project. Transplutonium organometa...
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RT @citrus_67: I have two #PhD positions open in my group:. One for domestic/international students (close date April 1):..
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Congratulations Haseena on her recent @InorgChem paper! An impressive piece of experimental and computational work! 🧪 ⚛️ 💎.
Now in @InorgChem! Spin crossover in a Co-iminosemiquinonate complex & versatility in Co oxidation/spin state & ligand oxidation/protonation state, new from @ColetteBoskovic @unimelb #SpinCrossover #RedoxActiveLigands .Read it here:
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RT @InorgChem: Now in @InorgChem! Spin crossover in a Co-iminosemiquinonate complex & versatility in Co oxidation/spin state & ligand oxida….
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RT @matteobriganti2: 📢📢We are hiring! A two-year post-doc position is available. If interested in ab initio high-throughput calculations,….
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