Andrew Boggiano
@acboggiano
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Postdoc at @UWMadison Cyclotron Group | PhD from @GT_CHEM @f_orbitals | B.S. @UWChemistry | lanthanides, actinides, XRD, XANES | he/him 🏳️🌈
Madison, WI
Joined August 2019
Very excited to share my recent publication on molecular Pr4+ now online at @angew_chem . Always a pleasure to collaborate with @bessvlai & @rcsabya and Sam Greer. Thanks team!.
onlinelibrary.wiley.com
A crystallographically characterized Pr4+ imidophosphorane complex is presented, [Pr4+(NPtBu3)4] (where tBu=C(CH3)3), which exhibits a pseudo-tetrahedral coordination geometry in the solid state....
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RT @ccdc_cambridge: From @acboggiano, @f_orbitals, and co-workers, the first crystal structures of Pr(v) complexes. The 5+ state was achie….
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RT @cenmag: Pushing the known limits of lanthanide oxidation, chemists have isolated praseodymium (Pr) in the +5 oxidation state. The findi….
cen.acs.org
Isolating the lanthanide in this oxidation state suggests a shift in some periodic tables
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RT @andrewhillchem: So excited to share that my first-first author paper is out now in @J_A_C_S! We demonstrated two-electron redox cycling….
pubs.acs.org
A five-coordinate chlorovanadium species supported by two redox-active N-phenyl aminophenol ligands was prepared. Experimental and computational data support formulation of this complex as [(Phap)(...
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RT @Johnseedo: Years in the making – 3-centre-1-electron trithorium metal-metal bonding. Out now in @NatureChemistry !. .
nature.com
Nature Chemistry - Superatoms are metal clusters that collectively behave like an atom, but they usually require metal–metal bonding and thus they are based on main group or transition...
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RT @Popov_Group: Happy to share the C&EN article on the first molecular Pr5+ complex! .Praseodymium powers up to 5 .
cen.acs.org
Isolating the lanthanide in this oxidation state suggests a shift in some periodic tables
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Excited to share the final version of Pr5+, now out in Nature Chemistry! Many thanks to co-authors, this was a huge lift from all fronts
nature.com
Nature Chemistry - The most common oxidation state for lanthanide elements is +3, and, beyond cerium, examples of these elements exhibiting higher oxidation states remain scarce. Now, a molecular...
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RT @ccdc_cambridge: From @DavideSpinnato2, @CornellaLab in @NatureChemistry, a tri-bismuth(i) equivalent of the allyl cation. This complex….
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RT @pchirik: Bringing back the 2 communication. My editorial in @Orgmet_ACS and links to the collection of those recently published. https….
pubs.acs.org
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RT @ACSINORDivision: Our next Periodic Table Talk is quickly approaching (1/15/2025 12 pm (Pacific), 3 pm (Eastern)). Register here: https:….
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RT @f_orbitals: Considering graduate research with actinides, or a career in the National Laboratories? Join us for the DOE/NNSA Graduate S….
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I will also be giving a poster tomorrow from 6-8 pm as part of SEMRC poster 754 😃.
Excited for the 52nd SouthEastern Magnetic Resonance Conference to start tomorrow morning as part as @sermacs2024. It will be an interesting mix of sNMR, ssNMR, MRI, and EPR :). Program below:.
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Excited for sermacs this week! Tomorrow @KaitlynOtte (10:30) myself (2:15) and @jenchem (3:55) will be presenting in the Advances in F-Element Chemistry Session.
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RT @DemirSelly: Super excited to present a remarkable electronic situation of the benzene dianion 🤩😊🥳. Three new inverse-sandwich rare eart….
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RT @sheepy1193: Now live in Inorg. Chem.@Kaysresearch foray into phosphanide ligands for the stabilisation of low coordinate metal complexe….
pubs.acs.org
Here, we report an improved synthesis of the bulky phosphanide anion [P(SiiPr3)2]− in synthetically useful yields and its complexation to group 12 metals. The ligand is obtained as the sodium salt...
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RT @Popov_Group: Hire alert! We have an opening for a postdoc position in the Popov group at WSU to work on the computational modeling of t….
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