Olefin_Metathesis
@Olef_Metathesis
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Human-run account focused on the latest research and applications of olefin metathesis. Questions or issues with OM? PM me
Joined April 2025
Catalytic Enantioselective C(sp3)���C(sp3) Cross-Coupling of Tertiary Nitriles with Allyl Halides to Quaternary Stereocenters featuring product valorization via #CM and #RCM (@J_A_C_S) https://t.co/b5hPMULl4M
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One-pot synthesis of sequence-controlled macromonomers via living anionic addition reaction and subsequent acyclic diene metathesis polymerization #ADMET (@ChemicalScience) https://t.co/iLU90AaAo3
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64Cu-Labeled Stapled (via #RCM) Peptide-Based Radiopharmaceuticals Targeting MDM2/MDMX for Pan-p53 Tumors (@ACSPublications) https://t.co/QY2ciK9UE4
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A Multiply and Long-Chain Branched Polyolefin with Low Density Polyethylene (LDPE)-Like Properties Containing Two Types of Functional Groups (@angew_chem) https://t.co/nVUj3KDkPz
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Evaluation of Steric and Electronic Parameters of NHCs on Vanadium Imido Alkylidenes for Olefin Metathesis (@BukhGroup)(@ACSCatalysis) https://t.co/CMhYXdiIH9
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Alkyl-9-BBN Reagents Promote Closed-Shell Nickel-Catalyzed Al-kylarylation Towards Sequence-Encoded Cyclooctene Monomers #ROMP (@EngleLab)(@pengliu_group)(@GuteGroup)(@ChemRxiv) https://t.co/cQqa1QGBoE
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Synthesis and Electrochemical Properties of Well-Defined Norbornene-B-ferrocene-dioxaborolane Hybrid Polymeric Material (@InorgChem) https://t.co/3sFjXFYIS8
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Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis #RCM (@J_A_C_S) https://t.co/Tw3IjVMWiK
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Cycloalkane Incorporation Into the 2′,4′-Bridge of Locked Nucleic Acid via a ring-closing metathesis #RCM (@JACS_Au) https://t.co/Gzv8xPvCBq
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Bidirectional Synthesis of C2-Symmetric Unilateral Substituted Acenes: 1,10,11,12-Tetrafluorotetracene featuring a very demanding #RCM step (@JOC_OL) https://t.co/YSofJIBhBG
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Stereocontrolled Divergent #TotalSyntheses of (+)-7-Deoxypancratistatin, (+)-7-Deoxy-trans-dihydronarciclasine, and (+)-Lycoricidine featuring #RCM (@JOC_OL) https://t.co/vKKyRVHztb
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This work made it to @JACS_Au
pubs.acs.org
A series of 38 chiral ruthenium complexes containing cyclic(alkyl)(amino)carbene (CAAC) ligands with axial C–N chirality have been developed. By merging axial and central chirality, very high...
Merging central and axial chirality in Cyclic(alkyl)(amino)carbenes: The keystone for high enantioselectivities in Ru-catalyzed asymmetric olefin metathesis (@Dylan_Bouetard)(@Rodolphe_Jazzar)(@ChemRxiv) https://t.co/bnvEnAaE5Q
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Next-Generation GLUT Inhibitors: Lactone to Lactam Conversion in Rapaglutin A Confers Resistance to Plasma Esterases #mRCM (@HopkinsMedicine)(@ACSPublications) https://t.co/30XhPAZ1TT
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Engineering Free Volume within Frontal Ring-Opening Metathesis Polymerization #FROMP via Pendent Group Plasticization (@ChemRxiv)(@LessardLab )(@JacobJLessard1) https://t.co/bZkZevEu6P
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Toward Iron-Catalyzed Alkene Metathesis: Mapping the Reactivity and Deactivation Pathways of an Iron Metallacyclobutane (@Aromaticist)(@deRuiterLabs) (@angew_chem) https://t.co/jFgVEkJnge
onlinelibrary.wiley.com
Iron-catalyzed alkene metathesis has long remained elusive. This study identifies β-hydride elimination from an iron metallacyclobutane as a key deactivation pathway in iron-catalyzed alkene metath...
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Ring-opening metathesis polymerization #ROMP-Derived Organoborane Polymers as Strong Lewis Acids and Luminescent Materials (@ChemEurope) https://t.co/IvwKadO0RD
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Molecular Weight Control in Frontal Ring-Opening Metathesis Polymerization (@angew_chem)(@LessardLab)(@JacobJLessard1) https://t.co/uHQVoX8uS0
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Oligomeric α-diimine nickel catalysts for enhanced ethylene polymerization (@ChinChemLett) https://t.co/3ToCwUApyQ
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Frustrated Lewis Pair-Mediated Catalyst Efficiency in #ROMP: Mechanistic Insights from Boronic Ester-Functionalized Monomers (@MacroJrnls_ACS ) https://t.co/YKCMN0vGHw
https://t.co/FoGyx1bx9c
pubs.acs.org
The ring-opening metathesis polymerization (ROMP) of boronic ester-functionalized monomers remains underexplored compared with other polymerization strategies, despite the unique physical and...
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A Convergent Approach to Phragmalin-Type Limonoids: #TotalSynthesis of Thaigranatin P featuring RCM for east fragment assembly (@NewhouseGroup)(@J_A_C_S) https://t.co/finQiWMmHC
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