Constantin G. Daniliuc
@GDaniliuc
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Senior scientist at University of Münster
Germany
Joined March 2022
We are happy to share or recent study "Boron-enabled Stereoselective Synthesis of Polysubstituted Housanes" added to @ChemRxiv. A huge congratulations to students and collaborators for their efforts. @GDaniliuc @DrGregor2 @funes_ardoiz @Boron_Chemistry
https://t.co/2xwqbuXM6j
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🚀Unlocking new frontiers in photocatalysis with #AI! Our latest @JACS paper presents a 3⃣-layer screening strategy for accelerated discovery of EnT-catalyzed dearomative cycloadditions!✨ Check this out: https://t.co/3mhITBNimH
#Photocatalysis #AIforScience #OrganicChemistry
pubs.acs.org
Visible-light-mediated energy transfer (EnT) photocatalysis has emerged as a highly appealing strategy for converting planar (hetero)arenes into complex, medicinally relevant, three-dimensional (3D)...
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Can AI accelerate reaction discovery in photocatalysis? We (@GloriusGroup) present a data-driven strategy to unlock the triplet-state reactivity of monocyclic heteroarenes, enabling EnT-catalyzed intermolecular dearomative cycloadditions. Now in @J_A_C_S!
pubs.acs.org
Visible-light-mediated energy transfer (EnT) photocatalysis has emerged as a highly appealing strategy for converting planar (hetero)arenes into complex, medicinally relevant, three-dimensional (3D)...
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3⃣-Layer Screening Strategy for Accelerated Discovery of Energy Transfer-Catalyzed Dearomative Cycloadditions ☀️⚗️ @J_A_C_S Highlight: ML-enabled substrate mapping as step 1⃣! #AI @GoogleAI
https://t.co/R1lnhtaXlK
pubs.acs.org
Visible-light-mediated energy transfer (EnT) photocatalysis has emerged as a highly appealing strategy for converting planar (hetero)arenes into complex, medicinally relevant, three-dimensional (3D)...
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ICYMI, from @ckerzig, @GloriusFrank and colleagues: 'Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range' 🔥 #OpenAccess 🔓 https://t.co/Ail9Ug4Q8D
pubs.rsc.org
Triplet–triplet annihilation photon upconversion (TTA-UC) provides a milder alternative to traditional UVB/UVC photochemistry. However, suitable sensitizer-annihilator pairs are scarce, in particular...
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Congrats, Till and the team! @ResearchTill It was my great pleasure working with you, Till. Cycloparaazine (Nature Commun. 2025): https://t.co/ZzQt5tHCW9 Press release from Nagoya U (also from RIKEN): https://t.co/o1tfeT3vYC
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The first all-azine nanoring is now out in @NatureComms. The very strong collaborative team of Nagoya-Munster-RIKEN made this possible, particularly Till Drennhaus @ResearchTill. Many thanks and congrats to all involved! https://t.co/HCHdf3wU1Y
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Nature research paper: C-to-N atom swapping and skeletal editing in indoles and benzofurans https://t.co/Esge2yFMfW
nature.com
Nature - C to N atom swapping in indoles is introduced that gives indazoles through oxidative cleavage of the indole heteroarene core and subsequent ring closure, adding another method to the field...
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C-to-N atom swapping and skeletal editing in indoles and benzofurans AK Studer - University Münster https://t.co/1Q190D3xt3
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C-to-N atom swapping and skeletal editing in indoles and benzofurans
nature.com
Nature - C to N atom swapping in indoles is introduced that gives indazoles through oxidative cleavage of the indole heteroarene core and subsequent ring closure, adding another method to the field...
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Check out one of our recent most read articles, from @GloriusFrank and colleagues: 'Lewis acid-catalyzed [2π+2σ] cycloaddition of dihydropyridines with bicyclobutanes' @GloriusGroup #openaccess 🔓 https://t.co/N3gHpTMgqz
pubs.rsc.org
Herein we report a simple BF3-catalyzed cycloaddition of dihydropyridines with bicyclobutanes for the expedient synthesis of novel three-dimensional azacycle-fused bicyclo[2.1.1]hexane scaffolds. The...
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New @ChemSocRev tutorial review! 🧪 NHCs on surfaces — chemistry at the interface 🚀 👉 Insights into the surface chemistry of NHCs- Check it out!! https://t.co/6MmUUENLXP
#NHC #SurfaceScience
pubs.rsc.org
N-heterocyclic carbenes (NHCs) have emerged as a versatile and powerful class of ligands in surface chemistry, offering remarkable stability and tunability when bound to surfaces, including metals,...
"Insights into the surface chemistry of N-heterocyclic carbenes" - tutorial review just published in @ChemSocRev NHCs on Surfaces😍: Multidisciplinary research field - Moving to the next level of Insight and Application!👩🔬🚀 https://t.co/HgHOuMK4Bq
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"Insights into the surface chemistry of N-heterocyclic carbenes" - tutorial review just published in @ChemSocRev NHCs on Surfaces😍: Multidisciplinary research field - Moving to the next level of Insight and Application!👩🔬🚀 https://t.co/HgHOuMK4Bq
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closo-CarBORanyl Analogs of β-Arylethylamines via EnT-Catalysis Beautiful (and potentially functional) icosahedral structures - just online @angew_chem
@GloriusGroup
https://t.co/fX0BQW4C8Z
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Now online & open access: Article by Mengjun Huang, Constantin Gabriel Daniliuc & Armido Studer Iron-catalysed radical Markovnikov hydroamidation of complex alkenes https://t.co/VYREVtnfCq
nature.com
Nature Synthesis - An iron-catalysed radical Markovnikov hydroamidation of alkenes using a cyanamide reagent is reported. The method achieves C–N bond formation with high yields and...
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Happy to share our work about this exciting strain- release and Bifunctional reagents (EnT-catalyzed) chemistry.🧪🥳Please have a look!!!
Bifunctional reagents and strain-release cycloaddition – one reagent for the best of both worlds! 🫱🏼🫲🏽 Check out our latest publication on cyclic bifunctional reagents and in situ generated 2H-azirines in @J_A_C_S : https://t.co/TnK2pbR7QI
#OrganicChemistry #ChemTwitter
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Surprise, surprise: Phenothiazine Sulfoxides as Active Photocatalysts! 💡⚗️💡Exciting 🚀collaboration between @WengerOliver group and @GloriusGroup published in @J_A_C_S : https://t.co/4PQcflOXKB
pubs.acs.org
N-substituted phenothiazines are prominent and highly effective organic photoredox catalysts, particularly known for their strong reducing capabilities. Despite their wide utility, the closely...
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Phenothiazine Sulfoxides as Active Photocatalysts for the Synthesis of γ-Lactones | Journal of the American Chemical Society @uni_muenster
@GloriusFrank @UniBasel_en @UniBasel @WengerOliver @GloriusGroup @TotalSyntheses
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Mechanism Switch Between Radical-Polar Crossover and Radical Buffering (Xiaotian Qi and co-workers) @GloriusFrank @GloriusGroup •
onlinelibrary.wiley.com
The radical buffering scenario, which features the reversible radical dissociation from alkyl chromium(III) followed by the metal-carbonyl-coupled (MCC) radical addition to form the C─C bond, is...
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The Effect of Regioisomerism on the TADF Properties of Organic Dyes by @RizzoFab1 and co-workers #OpenAccess @ChemEurJ 🔓
chemistry-europe.onlinelibrary.wiley.com
The properties of TADF emitters are highly dependent on the chosen electron donor and acceptor, as well as the π-system that links them together. Herein, we show that regioisomerism affects the...
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