Dr Anker
@DrAnkerLab
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Senior lecturer in Chemistry at Victoria University of Wellington. All things Lanthanide and Main Group.
Wellington, New Zealand
Joined July 2019
Proud to present a new oxidation state for benzene 😎🎉🥳: We isolated and studied the first benzene radical trianion embedded in an inverse-sandwich yttrium complex! Published in @angew_chem! Collaboration with @DriessLab! https://t.co/c7VdOL0uI6
@MSUChem @GroupDemir
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Jeremy and co’s paper on the 1st group 2 metal-alkane complexes has been accepted @J_A_C_S. Huge amount of work went into this one. Alkane C-H activation at the redox active Mg centre is the ultimate goal.⚗️#ozchem @AFOSR @Monash_Science @MonashChemistry
https://t.co/Wo5TvgkB8p
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Check out our work on the isolation of elusive f-element diphosphene (HPPH) complexes, the first heavier Group 15 analogue of f-element diazenes (HNNH) that were first reported over thirty years ago. @UoMChemistry
nature.com
Nature Communications - The parent diphosphene molecule is of fundamental interest, but its reactive nature renders it challenging to isolate, and current metal-stabilized derivatives are limited...
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The newest chapter in air-stable Ni(0): Ni(DQ)2 @ChemRxiv pre-print: https://t.co/ZgzW2vbqqf
@HarryHe88239850 @SongLinLab #BMSChemistry
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What a beautiful reaction… Powerful work from Y. Mutoh sen-sei🎉@IliesTeam @RIKEN_JP Check the edge article: Transient π-coordination enables nucleophilic borylation of simple arenes - now published in Chemical Science
pubs.rsc.org
Borylation of an arene typically proceeds via transition-metal-catalyzed C–H activation. We report here that transient π-coordination to chromium activates 1 equiv. of a simple arene towards nucleo...
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We are advertising for two PhD studentships in organometallic chemistry! Come and work with us from October 2026: Advert 2)
findaphd.com
PhD Project - PhD Studentship in C–H Functionalisation Using Polymetallic Complexes at Imperial College London, listed on FindAPhD.com
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Excited to share a new, formally divalent dysprosium bis(amide) complex 😎🥳😊🎉, studied via crystallography and CASSCF calculations, and its reactivity with tertbutylisonitrile and white phosphorous. https://t.co/bO2tKdh6Gs
@GroupDemir @MSUChem @GroupOdom @ACSPublications
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I also gave my talk in ACCC10. Discussion with Mathew Anker (@DrAnkerLab), Matthias Driess (@DriessLab), and Cameron Jones (@Jones_Research) after the talk was very fruitful to understand the properties of our new compounds.
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.@DrAnkerLab knocking it out of the park at the ACCC10 with some spectacular new results, soon to be published. Seems anything is possible!
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Synthesis, reactivity and nucleophilicity of carboranyl-B-Mg compound (@NatureComms): https://t.co/5goj4s4stq.
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Intermolecular Lithium η2-Alkene and κ2-Alkane Complexes: Synthesis, Bonding, and Facile Interconversion | Journal of the American Chemical Society
pubs.acs.org
In this work, an approach enabling the synthesis of η2-alkene lithium complexes (Carb2,4,6-iPr)Li(η2-L) (L = 1-octene, cyclohexene) is elaborated. For 1,5-hexadiene, the same approach results in a...
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Tune in today to hear Dr. Fabian Kallmeier explain how to enhance the nucleophilicity of aluminum anions, which he recently published in @ChemicalScience, in a brand new Research Spotlight episode! Link: https://t.co/qpfGjNy4ng Key paper: https://t.co/65f7NW8axk
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Great work by the Hill groups Masters and Summer students Alannah and Estelle - coupling organonitriles at an aluminium centre. Out now in @Orgmet_ACS. https://t.co/w3VxUa8DrA
pubs.acs.org
The C-tert-butyl substituted azacyclopropenylaluminate, [(SiNDipp)Al-η2-{NCt-Bu}K]∞ (SiNDipp = (CH2SiMe2NDipp)2) reacts with both aryl- and alkyl-substituted nitriles. In contrast to previously...
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In 2017, Mike Hill and team published the remarkable nucleophilic alkylation of benzene with neutral calcium alkyl complexes. Here we report their anionic equivalents, and show a switch in reactivity to superbasic - deprotonating benzene, twice! https://t.co/gl8uqpIMzW
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REDOX-REACTIVITY of Yb and Sm inverse sandwich benzene complexes. An interesting observation is that, depending on substrate, benzene(4-) can reduce Sm(III) to Sm(II). https://t.co/Hzy6EK1MMQ
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Thanks a lot for highlighting our recent work @NatureSynthesis !
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Can redox active, Lewis acidic magnesium Pac-man complexes form stable "adducts" with alkanes? Jeremy, Matt, Joe and co’s latest pre-print @ChemRxiv says ”Hell Yeah”! Alkane C-H activation by a main group metal incoming? https://t.co/Wp8w0yKJgp
#ozchem @ChemistryMonash @AFOSR
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Congratulations JT! Many congrats to grad student Jianqin Tang for successfully defending his doctoral thesis! Thanks to Mike Cowley & Meera Mehta for doing the honours. Some of JT’s B and Si chemistry attached: https://t.co/l9mDx79Fu7
https://t.co/HRElXo8BMw
@OxfordChemistry
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