
Andy ⌬
@AndyADX
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RT @angew_chem: Ligand-Enabled Chemo- and Regioselective Ir(I)-Catalyzed Intermolecular Hydrocarbonation of Allenes: Access to Branched Pro….
onlinelibrary.wiley.com
Ir(I) catalysts featuring the electron-deficient bisphosphine ligand dFppe promote the hydrocarbonation of allenes with precise control over the selectivity to yield highly valuable branched produc...
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RT @angew_chem: Iridium-Catalyzed Enantioselective Intramolecular Hydroarylation of Allenes: Formal Synthesis of (+)-Rhazinilam (Fernando L….
onlinelibrary.wiley.com
A highly enantioselective iridium-catalyzed hydroarylation of allene-tethered pyrroles and indoles that provides access to relevant heterocyclic systems bearing vinyl-substituted 3ry or 4ry stereoc...
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RT @EngleLab: atropisomers? positional isomers? both?. We present beautiful and curious class of molecules today in @ChemRxiv. 🧐🪞. https://….
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RT @MetBioCat: Last week, we have several of our group members (@RicardoRXIII, @danimarcosat, @AndyADX and @AlexRey_95) at @12smosbologna c….
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RT @xabierfortes: Como esta es mi cuenta personal, allá vamos. Prefiero pagar una multa a ser cómplice de un genocidio.
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RT @xabierfortes: Reflexiones en esta mañana de domingo:.-El Televoto se ha cargado Eurovisión. No hace falta ser un sagaz analista para sa….
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RT @MetBioCat: This friday, March 21st, we are back again in the CiQUS Seminar Room. this time, having @AndyADX at his PhD defense. Plea….
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RT @angew_chem: Catalytic Amino Group Transfer Reactions Mediated by Photoinduced Nitrene Formation from Rhodium-Hydroxamates (Sukbok Chang….
onlinelibrary.wiley.com
We investigated the photoinduced generation of Rh-acylnitrenoids and their catalytic nitrene transfer reactivity using thermally stable, yet photoactive Rh-hydroxamate. Combined EPR, mass, and DFT...
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RT @pengwanglab: SPOSiPs: Another type of diphosphine ligands based on spirosilacycle. Check out @JOC_OL | Organic Letters .
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RT @MetBioCat: We are so happy to see on-line this collaborative paper with @NevadoLab .Always such a pleasure to work with you 🤩. Congratu….
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RT @angew_chem: Gold(III) Auracycles Featuring C(sp3)-Au-C(sp2) Bonds: Synthesis and Mechanistic Insights into the Cycloauration Step (Cris….
onlinelibrary.wiley.com
A novel set of alkyl-gold(III) complexes is synthesized and their reactivity is explored. These species are susceptible to undergo intramolecular C−H auration under mild conditions. Experimental...
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RT @angew_chem: Photoinduced Group Transposition via Iridium-Nitrenoid Leading to Amidative Inner-Sphere Aryl Migration (Sukbok Chang and c….
onlinelibrary.wiley.com
We report a fundamental mechanistic study of photoinduced Ir-nitrenoid formation and inner-sphere group transposition reactivity using Ir-hydroxamates. By preparing thermally stable yet photoactive...
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RT @angew_chem: Skeletal and Mechanistic Diversity in Ir-Catalyzed Cycloisomerizations of Allene-Tethered Pyrroles and Indoles (Fernando Lo….
onlinelibrary.wiley.com
An iridium-catalyzed cycloisomerization of N-allenyl pyrroles and indoles is reported. The method, which is initiated by a C−H activation step, delivers a diversity of synthetically relevant azahet...
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RT @MetBioCat: 🧐Have a look at 'Catalytic Addition of C–H Bonds Across C–C π-Bonds' by @AndyADX Carlos Lázaro-Milla @qojoselm and @chem_FLo….
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RT @HoiminJung: Happy to share the full story on capturing Rh-acylnitrenoid intermediates! Thanks to @MatthewHorwitz1 and @SamiranDeb16 for….
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RT @AlertaNews24: 🇮🇱🇵🇸 | URGENTE - GUERRA ISRAEL-GAZA: Las Fuerzas de Defensa de Israel confirman el ataque a una ambulancia en Gaza, dicie….
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