Debjit/
@2Debjit
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Research Scholar @CSIR_NCL, Pune|| Madridistaš¤š
Pune, India
Joined October 2019
Counterintuitive Chemistry: Carbene Stabilization of Zero-Oxidation State Main Group Species | Journal of the American Chemical Society #JACSPerspective
pubs.acs.org
Carbenes have evolved from transient laboratory curiosities to a robust, diverse, and surprisingly impactful ligand class. A variety of different carbenes have significantly contributed to the...
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Our first Nitrene work recently published in @angew_chem Have a look. Cheers!!! CopperāStabilized Nitrene Radical in NāN Coupling: Facile Synthesis of Hydrazides and Pyrazole - Chakraborty - Angewandte Chemie International Edition - Wiley Online Library
onlinelibrary.wiley.com
Using a well-defined Cu(II)-catalyst [CuII(L1)Cl2] (1) bearing 2,6-bis(phenyldiazenyl)pyridine (L1) as ligand, the otherwise copper-stabilized electrophilic nitrenoid species is transformed to a...
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š Proud moment! Our Main Group team just published their 2nd paper in @JACS_Au! They uncovered how Oā activation mechanisms differ across P, Sb, and Bi - pushing the boundaries of main group chemistry š§Ŗ Read more:
pubs.acs.org
Electronic structureāreactivity relationships are fundamental to advancing the redox chemistry of main-group elements. Herein, we investigate a series of planarized C2v pnictogen complexes (Pn = P,...
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We will be taking two PhD students this semester. Interested candidates with PhD fellowships (CSIR/UGC/INSPIRE) are encouraged to applying through AcSIR portal as well as send email to me. For more details, please visit our website:
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How to make a carbophosphinocarbene with a carborane backbone? Check out our latest work @Uni_WUE in @angew_chem, which is dedicated to Prof. Don Tilley @TDTilleyGroup on the occasion of his 70th birthday. https://t.co/gD41MOi2wV
onlinelibrary.wiley.com
The ortho-carboranyl carbophosphinocarbene(CPC) was synthesized via a click-type reaction. Experimental and computational studies reveal its remarkable electron-donating ability. Reactivity studies...
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Thrilled to share! Check out our @angew_chem article on FLP-type small molecule activation by a stable azomethine ylide. Congrats @SudipBaguli
@sarkarsubham33 for the fab work! Thanks @ANRFIndia
@serbonline
@dcsiiserkol for $$ & infra. main group rocks! https://t.co/gwyHvGDqzF
onlinelibrary.wiley.com
An azomethine ylide is shown to activate a series of HāE (EāB, Si, Al, O) and BāB bonds in āFrustrated Lewis pairā (FLP)-like fashion. A transfer hydrogenation from NH3ā¢BH3 is also accomplished. DFT...
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Check out our first steps into the main group @ChemRxiv ! Pioneered by @ErrikosKounalis and in collab with @ME_Moret An N-Heterocyclic Germylene with a Versatile Metal-Binding Pocket: Insights into Heterodinuclear Bonding and Reactivity | ChemRxiv - https://t.co/Pl3nH0qziX
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published (Open Access): A Monomeric Diarylstannanone with a Sn=O Double Bond: Synthesis and Characterization https://t.co/46RX26EsZb
aces.onlinelibrary.wiley.com
An acid-base free stannanone featuring an authentic Sn=O double bond has been unveiled! The size-controllable Rind groups enable the systematic synthesis of diorganotin(IV) oxo compounds, including...
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The final day of ICMGSC 2025 got off to a grand start with a talk by Prof. Cameron Jones, Monash University. Low-valent alkaline earth metals and their applications to gaseous molecule activation was discussed! @Jones_Research @Chemie_iisertvm @RoySocChem @DaltonTrans #ICMGSC2025
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From Bis(borylene)-Substituted Xanthenes as Reactive Intermediates to Diboraoxirane Complexes (@J_A_C_S): https://t.co/gtcmE0d5Lr (@DriessLab).
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We have a couple of open positions for JRF with the possibility to convert to PhD program. Interested candidates are requested to reach out to me directly for more details.. For our research visit our lab webpage: https://t.co/rHsMi7J4w5
@csir_ncl
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A hexavalent nickel complex! Reductive addition of three Be-Be bonds at Ni(0) produces Ni(BeCp)6. @GroupAldridge
https://t.co/SUFbur8Nus
pubs.acs.org
High-valent nickel species are implicated as intermediates in industrially relevant chemical transformations and in the catalytic cycles of metalloenzymes. Although a small number of tetravalent NiX4...
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New Main Group Material Update!! Checkout our latest @angew_chem
#Happyreading
Our latest Angewandte paper - excellent collaboration between synthesis (@KritikaGour94 @2Debjit), theory (@SRDChem @KumarVanka1) and material team (Arup & Dipak). Thank you @angew_chem for super fast publication process! @csir_ncl @serbonline
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Addition of R- to CO is troubled by the instability of the acyl anion. Here we report an odd case of a highly selective three-fold addition to CO. Switching polarities converts a Mg alkyl into a Mg alkoxide complex. @olie_chem @ChemEurJ
https://t.co/tToRW7MZMM
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Check our recent article now out @DaltonTrans. #Happyreading
Latest work from our groups- led by @gargikundu6 and duly supported by @2Debjit @SRDChem, @rajeshgonnade & others -now out @DaltonTrans as part of a themed collection on Main Group Compounds in Materials and Catalysis. Thanks @csir_ncl & @serbonline
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Time to revise text-book chemistryš
Thrilled to share our new study of anti-Bredt olefins inĀ @ScienceMagazine. Congrats to the authors for this nicely timed study, 100 yrs after āBredtās Ruleā came to be. Read it here: https://t.co/mIgNnmJpws
@ucla @uclachem @houk1000
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I could not find any contact email or anything to confirm the status of the upcoming journey. The chat bot system is not at all convenient. Please reach out ASAP with the option regarding the travel itinerary.
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Hey! @AirIndiaX....I got an email early this morning that my scheduled flight IX1327 got cancelled due to bad weather conditions.....but I tried to contact the customer service I got directed to the chat box service with no end of the actual solution.
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I've always looked for a comprehensive review of d-block tetrylene/yne chemistry, but it didn't exist...until now!! š¤© This took an entire year to put together, SUPER happy that this HUGE 96-page review is now published in @ChemSocRev, check it out š https://t.co/N2vnVlSwCx
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