DM Research Group IISERK
@dmresearchgroup
Followers
748
Following
778
Media
6
Statuses
372
Synthetic organometallic chemistry for homogeneous catalysis
IISER KOLKATA
Joined September 2022
Durgapuja gift on the mahaastami evening! Thanks @DaltonTrans for publishing our 1st entry to low-valent Ge chemistry. Congrats @MondalMsumana93 @sarkarsubham33 and @Chhotan_ila for the effort. Thanks @ANRFIndia and @dcsiiserkol for the $$. Check it out!
pubs.rsc.org
A hybrid N-heterocyclic carbene (NHC)–fluorenyl ligand (L) supported GeIICl complex ([LGeCl]; 1) has been made from GeCl2(dioxane) and [LK]n. Compound 1 is reduced by Jones’ MgI2 dimer [(MesNacnacM...
4
4
48
Excited to share our recent article now published in @angew_chem where we explore the redox noninnocence nature of β-diketiminate ligand and electronic structure details for Cu based complex. Congratulations to @RahulSi98003214. @DCS_IISERMOHALI
onlinelibrary.wiley.com
The redox noninnocence of a β-diketiminate backbone has been evaluated for indole alkoxycarboxylation reactions, where the electron-rich ligand backbone steers the electron transfer reactions.
11
9
76
Thrilled to share another @InorgChem on an intriguing THF ring opening on Mg by a so called non-nucleophilic fluorenyl with a detailed computation. Congrats @Chhotan_ila @sarkarsubham33! thanks @ANRFIndia @dcsiiserkol for the $$. Do check it out!
pubs.acs.org
[9-{2-(dimethylamino)ethyl}fluorenyl] (L2)− is explored as a simple yet effective ancillary ligand for heteroleptic Mg chemistry. The proligand L2H reacts with [Mg(nBu)2(thf)x] to give [(L2)Mg(nBu)...
14
5
87
🌟 Small Steps, Big Wins 🤝 The ETOMC 2024 Special Collection is live! Featuring highlights from the @iiserkol conference on Organometallics & Catalysis, published in Small, Chemistry–An Asian Journal & EurJIC. https://t.co/vOBihxaTKs
@WileyGlobal @wileyinresearch @WileySTEM
0
4
21
Thrilled to share this giant piece of work @InorgChem on intramolecular Aryl-I/Br activation at a CAAC/NHC-bound coinage metal chloride. Congrats @SudipBaguli @soumajit_iiserk @sarkarsubham33! thanks @ANRFIndia @dcsiiserkol for the $$. Do check it out! https://t.co/U6eDWPj7Nc
pubs.acs.org
A cyclic(alkyl)(amino)carbene (CAAC; 1) with an iodobenzyl side arm and an analogous N-heterocyclic carbene (NHC; 2) are isolated by deprotonating their corresponding pyrrolinium and imidazolium salt...
12
6
91
One day in the year the Harder lab turns orange. Great Beer Tasting session with 12 beers from Holland, Belgium and France🍺🍺🍺🍺🍺🍺🍺🍺🍺🍺🍺🍺
0
3
54
Thrilled to share our review on 6-NHCs-co-authored with @gargikundu6-is out in @DaltonTrans! Highlights the developments made in our lab & global advances. Dedicated to my PhD supervisor Prof. Herbert Roesky on his upcoming 90th birthday! @csir_ncl
pubs.rsc.org
In recent years, there has been a remarkable surge in the utilization of saturated N-heterocyclic carbenes (NHCs) as ligands in main group chemistry. While the field has predominantly focused on...
17
11
106
It is our great pleasure to announce the 5th Spanish Workshop on Phosphorus Chemistry 👇It will be online on the next May 26th and 27th, register for free! @ViktoriaGessner @mariacaporali27 @Dr_Berionni @pcalleja515
4
21
78
Thrilled to share! Check out our @angew_chem article on FLP-type small molecule activation by a stable azomethine ylide. Congrats @SudipBaguli
@sarkarsubham33 for the fab work! Thanks @ANRFIndia
@serbonline
@dcsiiserkol for $$ & infra. main group rocks! https://t.co/gwyHvGDqzF
onlinelibrary.wiley.com
An azomethine ylide is shown to activate a series of H─E (E═B, Si, Al, O) and B─B bonds in “Frustrated Lewis pair” (FLP)-like fashion. A transfer hydrogenation from NH3•BH3 is also accomplished. DFT...
17
7
146
A new donor-functionalized NHO in the market! That too on a bismuth as the first ever NHO-Bi complex! Do check out our recent @DaltonTrans article! Congrats all the authors and thanks to @serbonline @ANRFIndia @dcsiiserkol for funding.
pubs.rsc.org
Herein, we report our previously developed bifunctional imidaozlium-phenol LH2Br ([HO-4,6-tBu2-C6H2-2-CH2{CH(NCH = CHNAr)}]Br; Ar = Dipp = 2,6-iPr2-C6H3), leading to three distinct outcomes with...
2
6
51
Thank you @dmresearchgroup for taking time to visit us here @IISERPune. We thoroughly enjoyed your talk on diverse cycloaddition reactivities of azomethane ylide at #IINCM2025 @ShabanaKhan01
0
8
49
Unforgettable moments and insightful discussions with an incredible team at the #ICMGSC2025! An exceptional event of scientific insights, connections and inspiration. Onward and upward! #ICMGSC2025 @tvmiiser @Chemie_iisertvm @RoySocChem @DaltonTrans @remulveygroup @Ghadwal_Group
2
29
164
Prof. Debabrata Mukherjee from IISER Kolkata delivered a stimulating talk on azomethine ylides. The application of frustrated lewis pairs to small molecule activation underlined the power of main group chemistry! @dmresearchgroup @tvmiiser @RoySocChem @DaltonTrans #ICMGSC2025
0
7
62
0
0
1
Happy to share! Excellent cationic Rh catalysts based on unusual hard donors like aziridine and pyrrolidone for hydrosilylation and hydrogenation. Thanks @serbonline & @dcsiiserkol for the support.
chemistry-europe.onlinelibrary.wiley.com
A pyridyl-tethered aziridine and a 2-pyrrolidone are shown as two unorthodox phosphine- and carbene-free ancillary ligands, whose cationic Rh(I) complexes prove highly effective in hydrosilylating...
5
4
43
📢ICMGSC 2025: Detailed Program Schedule https://t.co/KLaBdOH0lp
@tvmiiser @Chemie_iisertvm @RoySocChem @DaltonTrans @remulveygroup @Ghadwal_Group
@ChrisSlootweg @Francois_Gabbai @dmresearchgroup @rebecca_melen @harder_research @SangitK35711415 @SDRobertsonChem @KrossingGroup
📢ICMGSC 2025: Program Schedule Announced! The talks are well spread out from the beginning till the end to keep up the excitement among the audience befitting the conference theme! https://t.co/APADFrVwOF
@tvmiiser @Chemie_iisertvm @RoySocChem @DaltonTrans @remulveygroup
0
12
31
📢ICMGSC 2025: Program Schedule Announced! The talks are well spread out from the beginning till the end to keep up the excitement among the audience befitting the conference theme! https://t.co/APADFrVwOF
@tvmiiser @Chemie_iisertvm @RoySocChem @DaltonTrans @remulveygroup
ICMGSC 2025, 13-16 Feb 2025: Jointly organised by @tvmiiser and @RoySocChem Website is live! https://t.co/z2hq7kZQGq Updates to follow!
1
8
34
Can azomethine ylides be considered as Frustrated Lewis Pairs(FLPs)? Join today's intriguing talk by Prof. Debabrata Mukherjee (@dmresearchgroup) from @iiserkol to know the answer. #ISCHA2024 #FLP
1
4
39
A Durga puja gift right on time! It's a pleasure to dedicate this @DaltonTrans article on MgH with a dearomatized picolyl backbone to Prof. David Milstein @DavidMilstein7, the pioneer! Thanks @serbonline & @dcsiiserkol for the $. Congrats all the authors!
pubs.rsc.org
Heteroleptic magnesium hydrides are important for their stoichiometric and catalytic reduction chemistry. Their primary nucleophilic site is typically the hydride, while the ancillary ligands...
9
5
85
Delighted to share our 3rd @InorgChem this year! The work is purely based on chemical intuition. CAACCuCl for hydrosilylation catalysis. Some new CAACs are also in! Thanks @serbonline and @dcsiiserkol for the support. Congrats to all the authors!
pubs.acs.org
Cu-catalyzed carbonyl hydrosilylation involves a ligated “[(L)CuH]” as the active catalyst, where the ligand L has a crucial role toward the stability, stereoselectivity, and enhancement of the...
10
7
92