SCKao
@SCK64778810
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PDRA University of Oxford Rice Chem PhD
Joined April 2022
RT @ChemistryKoenig: We expanded our Bismuth LMCT methodology towards the direct decarboxylative C-N coupling of carboxylic acids with sulf….
chemistry-europe.onlinelibrary.wiley.com
Radical processes involving bismuth hold great potential, but innovative strategies are required to control the reactivity of bismuth intermediates. Herein, we report a direct photochemical decarbo...
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RT @JacobJAGarwood: I'm excited to share that my newest paper on radical polarity is out now in @J_A_C_S I'm grat….
pubs.acs.org
The polarity of a radical intermediate profoundly impacts its reactivity and selectivity. To quantify this influence and predict its effects, the electrophilicity/nucleophilicity of >500 radicals has...
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RT @J_A_C_S: Photodriven Ammonia Synthesis from Manganese Nitrides: Photophysics and Mechanistic Investigations | Journal of the American C….
pubs.acs.org
Ammonia synthesis from N,N,O,O-supported manganese(V) nitrides and 9,10-dihydroacridine using proton-coupled electron transfer and visible light irradiation in the absence of precious metal photoca...
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RT @LeonoriLab: Check out our most recent work in @J_A_C_S. Carboxylated amine-borane serves are boryl radical precursor in radical boryl….
pubs.acs.org
Alkyl organoborons are powerful materials for the construction of C(sp3)–C(sp2) bonds, predominantly via Suzuki–Miyaura cross-coupling. These species are generally assembled using 2-electron proces...
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RT @pushingarrows: Congrats on the amazing defense, Dr. kao!! @SCK64778810 I am so grateful for your amazing contributions to our group and….
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RT @soumyadip_hore: Excited to share our latest discovery, now published in the @J_A_C_S ! This study unveils a powerful combination of i….
pubs.acs.org
The strategic integration of organocatalysis with transition-metal catalysis to achieve otherwise unattainable stereoselective transformations may serve as a powerful synthetic tool. Herein, we...
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RT @J_A_C_S: Directed Hydrogen Atom Transfer for Selective Reactions of Polyenols | Journal of the American Chemical Society @TotalSynthese….
pubs.acs.org
Directed hydrogen atom transfer to alkenes is described. The process is catalyzed by iron complexes and allows for the site-selective hydrofunctionalization of polyenols. Experimental data suggest...
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RT @J_A_C_S: Enantioselective Synthesis of Allylic Sulfones via Rhodium-Catalyzed Direct Hydrosulfonylation of Allenes & Alkynes | Journal….
pubs.acs.org
A highly regio- and enantioselective hydrosulfonylation using commercially available sodium sulfinates is reported, providing the first direct asymmetric rhodium-catalyzed hydrosulfonylation of...
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RT @J_A_C_S: Fe/Thiol Cooperative HAT Olefin Hydrogenation: Mechanistic Insights That Inform Enantioselective Catalysis | JACS @pushingarro….
pubs.acs.org
Asymmetric hydrogenation of activated olefins using transition metal catalysis is a powerful tool for the synthesis of complex molecules, but traditional metal catalysts have difficulty with enanti...
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RT @ChiehYu_Chang: Excited to share the first application of Stack ligand in Rh-catalyzed reaction. The direct asymmetric hydrosulfonylatio….
pubs.acs.org
A highly regio- and enantioselective hydrosulfonylation using commercially available sodium sulfinates is reported, providing the first direct asymmetric rhodium-catalyzed hydrosulfonylation of...
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RT @isciverse: Fe/Thiol Cooperative Hydrogen Atom Transfer Olefin Hydrogenation: Mechanistic Insights That Inform Enantioselective Catalysi….
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RT @isciverse: Enantioselective Synthesis of Allylic Sulfones via Rhodium-Catalyzed Direct Hydrosulfonylation of Allenes and Alkynes. @J_A_….
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RT @J_A_C_S: Mechanism of Ni-Catalyzed Photochemical Halogen Atom-Mediated C(sp3)–H Arylation | Journal of the American Chemical Society @U….
pubs.acs.org
Within the context of Ni photoredox catalysis, halogen atom photoelimination from Ni has emerged as a fruitful strategy for enabling hydrogen atom transfer (HAT)-mediated C(sp3)–H functionalization....
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RT @Photocat_papers: Asymmetric photoredox catalytic formal de Mayo reaction enabled by sensitization-initiated electron transfer https://t….
nature.com
Nature Chemistry - The redox properties of visible-light-absorbing photosensitizers are limited by the energy of visible photons, but methods using sensitization-initiated electron transfer have...
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RT @NatureSynthesis: Now online:. Article by Yunfang Yang, @MarcGBQ, @xiongyih & co-authors. Engineering non-haem iron enzymes for enantios….
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RT @isciverse: Synthesis of Collidine from Dinitrogen via a Tungsten Nitride. @J_A_C_S #Chemistry #Chemed #Science #TechnologyNews #news #t….
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RT @_Picazo: !! Our group's first publication is now available in the J. Am. Chem. Soc.! We developed a scalable, iron-catalyzed cross-elec….
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RT @ChemistryKoenig: A call for sustainable chemistry! Discover water to make photoreactions with commercial Fe(II)/Fe(III) salts by adding….
pubs.rsc.org
Iron, mostly as Fe2+ or Fe3+ bound in oxides, is the second most common element in the Earth's crust after aluminium. Salts of the d-block metal are cheap and commercially available and have already...
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RT @NevadoLab: Our efforts to unlock the potential of Sulfinyl-Smiles for asymmetric alkene difunctionalizations now out in @NatureChemistr….
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RT @MatthewHorwitz1: This week Julianna Mouat @weixgroup joins us to share her work on the use of semiconductor quantum dots for cross-elec….
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