
So_Group
@SoGroup_NTU
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Official Twitter Account of the So Group at Nanyang Technological University Main-Group Chemistry Managed by graduate students
Singapore
Joined May 2021
RT @ccdc_cambridge: From @SoGroup_NTU, a carbene-stabilized four-membered silicon(0) cluster. Formed via reduction of carbene-SiCl4, the c….
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TGIF 🐭 Congratulations to Dr. Zhang Teng and team for their new work, out now on @angew_chem !! .
onlinelibrary.wiley.com
The silver–POM hybrid nanocluster [(n-Bu)₄N]₇[(C₆H₉)₆(PW₁₁O₃₉)₂Ag₁₃] features a unique three-layered {Ag₁₃}¹3⁺ core. Synergistic redox activity between the POM and silver enhances ROS generation via...
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Congratulations to @RahulSiwatch and Glenn for their new work, out now on @J_A_C_S !! 🥳 Strained Cyclic Alkyl(amino)carbene-Stabilized Tetraatomic Silicon(0) Cluster | Journal of the American Chemical Society
pubs.acs.org
Lewis-base-stabilized silicon species in the zero oxidation state are crucial for transforming elemental silicon into valuable compounds. The synthesis of a cyclic tetraatomic silicon(0) cluster,...
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RT @Boron_Chemistry: An N-Phosphinoamidinato Borasilenide: A Vinyl Anion Containing a B=Si Double Bond (@Chemicalscience): .
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Congratulations to Isabel and the team for their new work, out now on @ChemicalScience !! 🥳🥳. An N-Phosphinoamidinato Borasilenide: A Vinyl Anion Containing a B=Si Double Bond .
pubs.rsc.org
Borasilenes, which feature a heterodinuclear Si [[double bond, length as m-dash]] B double bond, show interesting reactivities, due to two proximal reactive sites—boron and silicon—each with distinct...
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RT @Boron_Chemistry: A Silicon Analogue of Fused Bicyclic Borirene Derivative (@ChemicalScience): .
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Congratulations to Isabel and the team for their work published now on @ChemicalScience !! Special thanks to our collaborators for their contributions to the DFT calculations 🥳. A Silicon Analogue of a Fused Bicyclic Borirene Derivative
pubs.rsc.org
The replacement of all carbon atoms in aromatic rings with main-group elements to afford inorganic ring systems is highly desirable due to their distinct aromatic character. However, fused polycyclic...
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RT @J_A_C_S: Isolable Spirocyclic Silylone: π-Delocalized Spiro[3.3]heptasila-2,6-diylidone | Journal of the American Chemical Society @NTU….
pubs.acs.org
Strained cyclic tetrylones are important synthons due to various synthetic applications. Connecting two cyclic tetrylone rings through a single shared quaternary group 14 element atom to form a...
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@RahulSiwatch @InorgChem Just realised a mistake, here's the actual link to the paper 😅😂:
pubs.acs.org
A digermanium(III) 1,2-dication comprises two cationic centers located at two interconnected Ge atoms. The strong Coulombic repulsion between two positively charged germanium cations hinders their...
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TGIF 🥳 Congratulations to Meldon & Shina for their new work, out now on @J_A_C_S !! Isolable Spirocyclic Silylone: π-Delocalized Spiro[3.3]heptasila-2,6-diylidone.
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RT @SoGroup_NTU: Congratulations to @RahulSiwatch for his work, out now on @InorgChem! 🥳.A Digermanium(III) 1,2-Dication Stabilized by Amid….
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Congratulations to @RahulSiwatch for his work, out now on @InorgChem! 🥳.A Digermanium(III) 1,2-Dication Stabilized by Amidinate and cAAC-Phosphinidenide Ligands | Inorganic Chemistry
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Congratulations to @FanJun_Chem & An Ping for their new work, out now on @NatureComms !!! 🥳.Carbon dioxide capture and functionalization by bis(N-heterocyclic carbene)-borylene complexes
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RT @Boron_Chemistry: NHC-Silyliumylidene Cation-Catalyzed Hydroboration of Isocyanates with Pinacolborane (@InorgChem): .
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Congratulations to Nicholas and colleagues for the wonderful work of NHC-Silyliumylidene Cation-Catalyzed Hydroboration of Isocyanates with Pinacolborane currently out on @InorgChem 🥳.
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RT @J_A_C_S: Tetrakis(N-heterocyclic Carbene)-Diboron(0): Double Single-Electron-Transfer Reactivity @NTUsg @Boron_Chemistry #NHC #Diboro….
pubs.acs.org
The use of 1,3,4,5-tetramethylimidazol-2-ylidene (IMe) to coordinate with diatomic B2 species afforded a tetrakis(N-heterocyclic carbene)-diboron(0) [(IMe)2B–B(IMe)2] (2). The singly bonded B2 moiety...
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