Gaurav Joshi
@Joshi11Gaurav
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Check out our recent article on VEC-driven contraction of the P6 ring in triple-decker complexes! @JemmisLab @iiscbangalore #Phosphorus #Chemistry.
Valence Electron Dependent Contraction of P6 Ring in [(CpM)2(μ,η6:η6-P6)] (M ═ V, Mo): A DFT Study (Eluvathingal D. Jemmis and co-workers @Joshi11Gaurav, @JemmisLab) •
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RT @ab_sirohiwal: Excited to be awarded the distinction of heading a Max-Planck Partner Group of MPI für Kohlenforschung at @iiscbangalore….
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RT @JindalLab: Congratulations to Reena @balhara_reena on successfully defending her PhD thesis! We sincerely thank Prof. Kumar Vanka @Kuma….
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RT @RominGogoi: I’m delighted to share that I’ve been selected as one of the participant to attend the 74th Lindau Nobel Laureate Meeting i….
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RT @JindalLab: An account detailing our research on metal-associated enols as key intermediates in controlling enantioselectivity in carben….
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RT @Suvam_FCB10: Check out our latest publication on “Cooperative B–H Activation: Ligand Diversity in Groups 6 and 8 Transition Metal κ2-N,….
pubs.acs.org
The synthesis, structure, and reactivity of the N-heterocyclic carbene (NHC)-supported κ2-N,S-chelated ruthenium complex [(IMe)(PPh3)Ru{κ2-N,S-(mbz)}2] (IMe = 1,3-dimethylimidazol-2-ylidene, mbz =...
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RT @angew_chem: Stabilization of Ethane-Like Dianionic Diborane(6) in Monometallic Titanium Complexes and its Subsequent B(sp3)-B(sp3) Bond….
onlinelibrary.wiley.com
Ethane-like classical dianionic diborane(6) species stabilized by mononuclear Cp*Ti have been isolated and structurally characterized. Treatment of these diborane(6) species with [M(CO)5 ⋅ THF]...
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RT @GhoshLaB_IITM: Can we cleave electron precise B-B bond of Diborane(6)? .Check our recent article now published in @angew_chem to find o….
onlinelibrary.wiley.com
Ethane-like classical dianionic diborane(6) species stabilized by mononuclear Cp*Ti have been isolated and structurally characterized. Treatment of these diborane(6) species with [M(CO)5 ⋅ THF]...
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RT @SoumenGiri2401: Glad to share our recent article published in Angew. Chem. Let's have a look. Congratulations to Bean da, Gourav bhai,….
onlinelibrary.wiley.com
Ethane-like classical dianionic diborane(6) species stabilized by mononuclear Cp*Ti have been isolated and structurally characterized. Treatment of these diborane(6) species with [M(CO)5 ⋅ THF]...
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RT @balhara_reena: Thrilled to share our new research in @ChemCommun on the significance of catalyst frameworks and non-covalent interactio….
pubs.rsc.org
Fe-based catalysts as well as enzymes typically yield low stereoselectivity for carbene insertion into X–H bonds. Here, we have utilized DFT methods to understand the mechanism and unusually high...
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RT @JindalLab: Our group’s review on carbene insertion mechanisms and stereoselectivity is now published in Chemical Society Reviews! Big s….
pubs.rsc.org
Constructing highly proficient C–X (X = O, N, S, etc.) and C–C bonds by leveraging TMs (transition metals) (Fe, Cu, Pd, Rh, Au, etc.) and enzymes to catalyze carbene insertion into X–H/C(sp2)–H is a...
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RT @hydride_papers: B–H Bond Activation in a Rh(III) Hydrido Borohydride Complex [Rh(H)(K2-BH4)tBu4(PNCNP)] Gives a Rh(I) σ-Dihydrogen Comp….
pubs.acs.org
Rh(III) pincer hydrido chloride and borohydride complexes [Rh(H)CltBu4(PNCNP)] (1) [tBu4(PNCNP) = 2,6-bis((di-tert-butylphosphaneyl)amino)benzen-1-ide] and [Rh(H)(K2-BH4)tBu4(PNCNP)] (2) have been...
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The Quest for Stable Borozene Core in Main-Group Capped Inverse Sandwich Complexes, [(HE)2B6H6]2- (E=B, Al, Ga, In, and Tl) (@Joshi11Gaurav, Eluvathingal D. Jemmis @JemmisLab and co-workers @iiscbangalore)
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RT @ChemEurJ: The Quest for Stable Borozene Core in Main-Group Capped Inverse Sandwich Complexes, [(HE)2B6H6]2- (E=B, Al, Ga, In, and Tl) (….
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RT @kar_sourav: Check out our account, published in Acc. Chem. Res. @ACSPublications. We have introduced a new way to look at boron rings.….
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RT @GhoshLaB_IITM: Can boron form flat rings?.Check our recent review now published in Acc. Chem. Res. to find out. Thanks to our collabor….
pubs.acs.org
ConspectusUnlike carbon, boron does not usually form ring compounds due to its electron-deficiency-driven affinity toward polyhedral geometries. The polyhedral boranes having closo-, nido-, arachno-,...
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RT @SoumenGiri2401: Glad to share our recent review published in ACCR in collaboration with prof. Himmel and prof. E.D jemmis. Congratulati….
pubs.acs.org
ConspectusUnlike carbon, boron does not usually form ring compounds due to its electron-deficiency-driven affinity toward polyhedral geometries. The polyhedral boranes having closo-, nido-, arachno-,...
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RT @subhashb818: Happy to receive the best poster award in @etomc2024 at @iiserkol. Congratulations and thanks to @SoumenGiri2401, @Joshi11….
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RT @ATBijuLab: We can now use BCBs as enophiles in a mild & selective Sc(OTf)3-catalyzed ene reaction with thioindolinones, just out @Chemi….
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RT @_upadhyayaarti: Check out our recent article, Anticancer Profile of Coumarin 6-Based Ir(III) Photocatalysts under Normoxia and Hypoxia….
pubs.rsc.org
Herein, we have designed, synthesized, and characterized two novel coumarin-6-based Ir(iii) photo-catalysts viz. [Ir(CO6)2(dppz)]Cl (Ir1) and [Ir(CO6)2(aip)]Cl (Ir2), where CO6 = coumarin 6, dppz =...
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