A thermodynamics-controlled epitaxial growth strategy enables the precise coating of Cs4PbBr6 onto NaYF4:Yb,Tm UCNPs, achieving structural evolution from core-shell to UCNP-in-LHP solids heterostru...

A synergistic strategy based on embedding heptagons and incorporating carbazole derivatives has been developed to create helical bilayer molecular carbons with a high fluorescence quantum yield...

We demonstrate that the OER performance of Li–O2 batteries primarily depends on the orbital interaction mode between the catalyst and the intermediates. In contrast to the strong Cd 4dxy–O 2Px/y...

By harnessing chalcogen bonding (ChB) catalysis, an exclusive access into a highly stereoselective strain-release C-glycosylation pathway was discovered. This was surprisingly not replicable by the...

The influence of various p-block element motifs on the photophysical properties of conjugated inorganic-organic hybrid polymers is surveyed regarding applications in organic electronics. Recent...

A metal-free nitrosation process enables direct C–H functionalization of polyethylene (PE) with high selectivity, producing either oxime- or carbonyl-functionalized polymers. Using t-BuONO under...

This work presents the first Sorp-vection-based membrane separation for silicone oil purification, coupling sorption-driven selectivity with convective transport. Our strategy enables highly select...

This study utilizes dual self-promoted polymerization to construct helical cationic polymers. Unlike conventional polypeptides where cationic side chains typically disrupt helicity, these cationic...

The reversible redox mechanism between O2 and ZnO (discharge products) of a novel aprotic zinc–oxygen (Zn-O2) battery chemistry. This discovery indicates that ZnO—typically an insulating byproduct...

We report a counteranion-controlled Rh-catalytic system for the chemodivergent functionalization of alkenes via C(sp3)─S bond cleavage. The use of Rh(COD)2OTf promotes Markovnikov transfer-hydrothi...

Electrooxidation enables tunable halocyclization of ambident amides, yielding either C–O or C–N products through ionic or radical pathways, respectively. While detailed experimental and analytical...

Sulfilimines are emerging as valuable functional group in modern medicinal chemistry. Yet, their catalytic preparation is underexplored compared to sulfoximines. Here, the iron-catalyzed synthesis...

Nearly identical molecular modifications of two differently shaped cuprous oxide via click chemistry lead to a striking divergence in product selectivity in CO2 electrolysis—favoring either methane...

Aryl boronic acids are key in building new molecules, but their direct conversion to radicals with electricity has been challenging. This work uses alternating polarity electrolysis and fluoride to...

This work demonstrates the on-liquid surface synthesis of crystalline 2D polyimine films by leveraging a fluorinated surfactant and a binary solvent mixture of DMAc-H2O. In situ grazing incidence...

Integrated Rh–MoRhOx cluster heterostructures on InGaN/GaN nanowires facilitate efficient charge extraction and spatially coupled hydrogen and oxygen evolution reactions, thereby fundamentally...

We develop new bifacial chiral non-fullerene acceptors (NFAs) for organic solar cells (OSCs). Through comparative investigations of four NFAs including meso, racemic, and chiral entries, we demonst...

Dreiklang is a reversibly switchable fluorescent protein with a unique photohydration/dehydration mechanism. Using complementary transient absorption and femtosecond—microsecond transient IR, we...

Self-generated oxygen vacancy in TiO2−x brought by BNF leads to different electron densities of adjacent Ti sites which achieved C2H5OH record yield of 51.4 µmol g−1 h−1 with a global selectivity of...