
Angewandte Chemie
@angew_chem
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Angewandte Chemie, a journal of the German Chemical Society (GDCh, @GDCh_aktuell) - a leading journal in #chemistry published by @WileyVCH in @Weinheim
Weinheim, Germany
Joined September 2008
Published in #AngewandteChemieNovit: Global optimization via machine learning interatomic potentials enables identifying more realistic and stable of supported nanoparticles. By Tibor Szilvási & co-workers (@SzilvasiGroup). Read it here:
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Construction of Fused–Bridged Tricycles by Molecular Reorganization Involving Prins Cyclization/Dicycloexpansion (Tong-Mei Ding and co-workers) #angewandteVIP •
onlinelibrary.wiley.com
A cascade Prins cyclization/dicycloexpansion of cycloalkylidene-tethered cycloketones (or their dimethoxy ketal form) was developed to synthesize fused-bridged tricyclic ring systems with consecuti...
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Lattice-Engineered Lanthanide Nanocrystals with Tunable Near-Infrared-IIb Lifetime (Qiangbin Wang and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
Engineering the lattices from distorted to strain-graded in lanthanide nanocrystals (LnNCs) via controllable cation intermixing (Ca2+, Ln3+), the multi-phonon orbit-lattice relaxation (MPR) between...
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Engineering Energy Dissipation Pathway via Topological Design: Toward Tunable Macroscopic Mechanical Performances of Dynamic Polymer Networks (Zhaoming Zhang and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
We leverage orthogonal host–guest recognition and metal-ligand coordination to construct SPNs and MINs with distinct topological cross-linked architectures, which perform divergent energy dissipati...
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Molecular Afterglow of Lophine-Based Luminophore and Its Imaging Applications (Chongzhao Ran and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
We discovered that lophine—the first historically documented chemiluminescent compound—can be converted from weak chemiluminescence to bright molecular afterglow by caging its imidazole moiety. This...
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Molecular Junction Polyoxotungstate-based Copper-Organic Frameworks for Photocatalytic Cross-Dehydrogenative Coupling (Ya-Qian Lan and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
A series of molecular junction polyoxotungstate-based copper-organic frameworks (i.e., Cu-POMOF-1, Cu-POMOF-2, and Cu-POMOF-3) have been successfully prepared and characterized that can be utilized...
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Electron Delocalization-Driven Dual-Electron Redox Chemistry in NiCo-LDH for High-Capacity Aqueous Ni–Zn Batteries (Xihong Lu and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
The introduction of cobalt into the Ni(OH)2 lattice facilitates the generation of charge-transfer orbitals through delocalized electrons near the Fermi level. In addition, the ultrathin structure...
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Synthesis and Application of Bioactive N-Functionalized Aziridines (David C. Powers and co-workers) #AngewandteReview #openaccess 🔓
onlinelibrary.wiley.com
This review discusses modern synthetic methods for the preparation of aziridine-containing small molecules, including biocatalytic, electrocatalytic, and photocatalytic strategies. We highlight the...
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N,O-Alternant Belt[3]arene Utilized for Construction of Multi-Color Supramolecular TADF Materials and Highly Selective Detection of 2-Cyanopyrazine (Chuan-Feng Chen and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
Starting from a new macrocyclic arene, 3,6-dimethoxycalix[3]acridine (3,6-DMO-C[3]A), N,O-alternant belt[3]arene (NOAB[3]A) was conveniently synthesized and successfully utilized to construct...
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Asymmetric Radical Coupling to Form β2,2,3-Amino Acid Esters by Synergistic Chiral Phosphoric Acid and Photocatalysis (Wen-Jing Xiao and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
A mild, modular approach is described for the stereocontrolled assembly of structurally complex β2,2,3-amino acid esters, overcoming long-standing limitations in substrate scope and reaction effici...
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Paired Pulse Electrocatalytic Conversion of Phenol for Co-Production of Cyclohexanol and Para-Benzoquinone (Buxing Han and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
The proposed paired pulse system achieves the selective conversion of phenol in wastewater for co-production of valuable cyclohexanol and para-benzoquinone, with an unexpected Faradaic efficiency of...
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Design of Aminophosphine Precursor for Robust Synthesis of InP Quantum Dots with Near-unity Quantum Yield (Min-Jae Choi and co-workers) #openaccess 🔓
onlinelibrary.wiley.com
Alkylsiylamine-based aminophosphine precursor was newly introduced to synthesize InP quantum dots (QDs). This new aminophosphine showed a faster reaction process compared to the conventional aminop...
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Fluorine. π Induced Alkyne Concentrating and Orderly Arranged Sulfonate-Adjusted Interfacial Water Structure Promote Alkene Electrosynthesis at Large Current Densities (Cuibo Liu and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
Nafion ionomer-modified palladium nanotips are designed to achieve electrocatalytic semihydrogenation of alkynes with an 83% Faradaic efficiency (FE) at −100 mA cm−2. The F···π effect induces the...
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A Natural Oxygen-Harvesting Electrode Enables Aeration-Free Electrochemical Advanced Oxidation for In Situ Water Remediation (Juan Wang and co-workers) •
onlinelibrary.wiley.com
An aeration-free electro-AOP system is developed using a dual-cathode design featuring a natural oxygen-harvesting electrode (NOHE) with a superhydrophobic, microporous structure. By capturing...
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Tailoring the Oxygen Vacancy Distribution in Se-Doped RuOx to Enhance Its Stability in Acidic Water Electrolysis (Zipeng Zhao and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
The impact of oxygen vacancy (VO) distribution on Ru oxide stability is unclear. We propose a strategy to tailor the distribution of VOs (VOs located away from Se dopants) via urea-assisted synthes...
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Organic Spin-State Photoswitches (Oliver Dumele and co-workers) #AngewandteReview #openaccess 🔓
onlinelibrary.wiley.com
Spin-state photoswitching has become a field of broad interest in the last decades due to unique physical and chemical properties accessible from controlling the spin state of a molecular entity....
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Multivariate Sulfate-Pillared Metal Azolate Frameworks with Tunable Flexibility for CO2 Capture from C2 Hydrocarbons (Yue-Biao Zhang and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
Suppressing flexibility for CO2 capture: The multivariate functionality approach precisely modulates the structural flexibility of sulfate-pillared metal azolate frameworks, enhancing their selecti...
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Ligand-Enabled Chemo- and Regioselective Ir(I)-Catalyzed Intermolecular Hydrocarbonation of Allenes: Access to Branched Products with All-Carbon Quaternary Centers (Fernando López and co-workers) @AlexRey_95 @AndyADX @metbiocat @ciqususc #openaccess 🔓
onlinelibrary.wiley.com
Ir(I) catalysts featuring the electron-deficient bisphosphine ligand dFppe promote the hydrocarbonation of allenes with precise control over the selectivity to yield highly valuable branched produc...
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One-Step Solvent-Assisted Cation Exchange Approach to Hollow #MetalOrganicFramework|s Nanoreactors with Orderly Distributed Active Sites for Tandem Catalysis (Xiaoyu Yang and co-workers) #AngewandteVIP •
onlinelibrary.wiley.com
Multifunctional hollow MOF nanoreactor, Pd@H-UiO-66-NH2, which contains precisely encapsulated Pd nanoparticles inside cavities, was controllably synthesized through one-step solvent-assisted cation...
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Space-Confined Electrocatalysis for #WaterSplitting: Synthesis, Performances, and Reaction Mechanism of Nanomaterials Toward High-Performance Catalysis (Jong-Beom Baek and co-workers) #AngewandteReview #openaccess 🔓
onlinelibrary.wiley.com
Schematic representation of dimensionally confined nanocatalysts (1D to 3D) for electrocatalytic water splitting, which represents a sustainable route for green hydrogen generation. Space-confined...
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Accelerated Porosity Screening Using a Multichannel Colorimetric Array (Andrew I. Cooper and co-workers) #AngewandteVIP #openaccess 🔓
onlinelibrary.wiley.com
A high-throughput porosity screening method was developed for rapid porosity evaluation, offering a cost-effective and scalable approach to identifying candidate porous materials that is 30 times...
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