Here, a [3 + 10] non-closed macrocycle was serendipitously self-assembled, incorporating two monovalent diamines, each with an unreacted amino group. These are selectively removed via imine exchange,...

Analytical and Bioanalytical Chemistry - Medical devices are generally made of polyvinyl chloride plasticized by six authorized plasticizers as alternatives to di-(2-ethylhexyl)-phthalate (DEHP)...

An overcrowded ethylene composed of electron-donating anion and electron-accepting cation shows multiple NIR chromisms accompanying the conformational change between folded and twisted conformers....

In multimetallic compounds, N2 typically bridges late transition metals in an end-on (η1:η1) fashion while early transition metals often bind N2 side-on (η2), with the latter resulting in more...

Reductive N2 cleavage at an acridane PNP pincer-supported Mo center leads to the first crystallographically characterized example of an unusual Mo(IV) nitride species featuring a bridging N2 coordi...

Although various skeletons of organic ligands have been applied to achieve the structural diversity of metallasupramolecular assemblies, limited approaches are available for organometallic cluster-...

Humanity’s replacement of fossil-fuel energy with renewable electricity will require extensive deployment of lithium batteries, which necessitates an increase in the rate of production of this vital...

Communications Chemistry - Wacker oxidation is widely used to convert alkenes to carbonyls, but selective oxidation of unbiased internal alkenes can be difficult. Here a nickel-catalyzed alkene...

Tubular structures with nanosized pores have shown remarkable applications in areas such as ion transport and water filtration, but their development is often hindered by challenges including low...

The ability to precisely modify the structure of molecules is a captivating process that has fascinated the synthetic organic and medicinal chemistry communities. To this end, functional group...

Despite their significant potential in organometallic chemistry, the utility of arsines as ligands in transition-metal catalysis remains underexplored relative to their phosphine counterparts....

Host–guest complexation enhances or even alters photoreaction selectivity by preorganizing substrates within the host’s confined cavities. Since most previous hosts exhibited no visible-light...

Threefold symmetric hexa-cationic hydrazone cages coordinate a range of transition metal ions upon deprotonation. When the cage contains ethyl solubilising groups the expected threefold symmetric...