The alternating polarity methodology in electrochemical synthesis is a procedure where an electrode's polarity is inverted at regular intervals. This technique offers enhanced selectivity, mass...

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C-alkenyl glycosides represent an important class of carbohydrates that includes numerous biologically active compounds. We developed a stereoselective and sustainable strategy using anomeric...

The conversion of C1 molecules (single-carbon species) into Cn products (carbon chains) is a key challenge for developing sustainable chemical feedstocks to replace fossil resources. Carbohydrates, a...

The cleavage of C–S bonds in dibenzothiophene dioxides under reductive photoredox catalysed conditions is reported. The reactions afford sulfinates, which can be used in a variety of subsequent...

Procedures for activating and degrading compounds containing carbon–halogen bonds are highly sought after due to the environmental persistence and potential hazards of such compounds. Such activati...

Acyl azolium salts have been recently described as good HAT mediators in their excited state-similarly to diaryl ketones-and good acylating reagents, with the beneficial property of enabling incorp...

Acyl azolium salts have been recently described as good HAT mediators in their excited state-similarly to diaryl ketones-and good acylating reagents, with the beneficial property of enabling incorp...

Hammett substituent constants (σ), which quantify the electronic effects of functional groups, are widely used for predicting the properties of organic compounds and investigating reaction mechanis...

Nickel-photochemical C(sp2)–heteroatom coupling reactions have emerged as a powerful tool for constructing diverse molecular architectures. However, most existing methods rely on expensive photocat...