Cage Papers
@POC_Papers
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I am a bot digging out papers on molecular/supramolecular cages, organic or coordination. Maintained by @linjiangchen
Joined April 2017
Porous organic cages are rare treasures. Current search: organic/coordination/molecular/supramolecular cages
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Air‐Stable Radical Organic Cages as Cascade Nanozymes for Enhanced Catalysis
onlinelibrary.wiley.com
A tandem reaction with an enhanced rate is achieved by an air-stable radical cage reactor, in which the dual active sites (radicals as peroxidase mimics; Au clusters as glucose oxidase mimics) are...
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Porous Organic Cage Induced Spontaneous Restructuring of Buried Interface Toward High‐Performance Perovskite Photovoltaic
advanced.onlinelibrary.wiley.com
Porous organic cage (POC) is introduced between tin dioxide and perovskite to spontaneously reconstitute the buried interface. Through polydentate chelation and host-guest interaction between POC...
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Highly efficient Förster resonance energy transfer between emissive tetraphenylethylene-based metal–organic cage and the encapsulated dye guest
pubs.rsc.org
The host–guest strategy presents an ideal way to achieve efficient Förster resonance energy transfer (FRET) by forcing close proximity between an energy donor and acceptor. Herein, by encapsulating...
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Synthesis of Triarylborane-Centered N-Heterocyclic Carbene Cages with Tunable Photophysical Properties
pubs.rsc.org
Triarylborane-based discrete metal-carbene supramolecular cages [M3(1)2](PF6)3 (M = Ag, Au) were synthesized and characterized. The new hexacarbene assemblies show a significant solvatochromic effect...
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Mechanoresponsive Metal‐Organic Cage‐Crosslinked Polymer Hydrogels
chemistry-europe.onlinelibrary.wiley.com
The utilization of homobifunctional poly(ethylene glycol) chains terminally substituted with bipyridines as ligands for Pd6L4 cages enabled crosslinking of the metal-organic cages and subsequent...
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Anion‐Driven Programmable Chiral Self‐Sorting in Metal‐Organic Cages and Structural Transformations between Heterochiral and Homochiral Cages
chemistry-europe.onlinelibrary.wiley.com
An unprecedented tunable selectivity in chiral self-sorting is achieved in the formation of Pd2L4 cages. Anions encapsulation dictates the outcome of diastereomer selectivity, either meso-cage or...
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Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis
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Access to Amide‐linked Organic Cages by in situ Trapping of Metastable Imine Assemblies: Solution Phase Bisamine Recognition
chemistry-europe.onlinelibrary.wiley.com
The majority of shape-persistent self-assembled organic cages are accessed via precipitation and studied in the solid state. Herein, we show that metastable imine cages (unsuitable for precipitatio...
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Enantioselective fullerene functionalization through stereochemical information transfer from a self-assembled cage
nature.com
Nature Chemistry - The enantioselective functionalization of C60 is highly challenging, typically requiring complex chiral tethers or demanding chromatography. Fullerenes have now been shown to...
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Conjoined and non-conjoined coordination cages with palladium(II) vertices: structural diversity, solution dynamics, and intermolecular interactions https://t.co/pvyPYMBPSN
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Insight into Ion Transport in Discrete Frameworks of Porous Organic Cage Membranes
pubs.acs.org
Porous organic cages (POCs) of discrete frameworks are promising candidates for separation membranes of high ion permeability and selectivity. Here, we investigate the ion transport properties of POC...
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Metal–Organic Cage Extended Amorphous Network via Anionic Organic Linkers for Cr2O72– and Iodine Adsorption on Nanopores
pubs.acs.org
The covalent linking of metal–organic cages (MOCs) with a nanoscale cavity is an efficient strategy to construct functional materials with different properties compared with bulk MOCs, but studies...
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A Platinum(II)‐Based Molecular Cage with Aggregation‐Induced Emission for Enzymatic Photocyclization of Alkynylaniline
onlinelibrary.wiley.com
The photocyclization of alkynylanilines catalyzed by an aggregated PtII-based octahedral cage has been shown to mimic bio-enzyme catalysis by aggregated biological macromolecules. The aggregated...
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Two Pseudo-T Polyoxometalate–Organic Cages with the TdKeggin Template
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Charge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster
onlinelibrary.wiley.com
An unusual Cu3I4− based coordination cage was synthesized by a reaction between copper (I) iodide and a tripodal cationic ligand. X-ray structural evidence demonstrates that this cage can selective...
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Altering the Properties of Spiropyran Switches Using Coordination Cages with Different Symmetries
pubs.acs.org
Molecular confinement effects can profoundly alter the physicochemical properties of the confined species. A plethora of organic molecules were encapsulated within the cavities of supramolecular...
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Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages
pubs.rsc.org
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(ii) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)coba...
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Highly efficient bromine capture and storage using N-containing porous organic cages https://t.co/PunYo1WmO2
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