Organometallics
@OrganoMetalsPD
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The applied organometallics group of the University of Padua is a young and dynamic group that enthusiastically carries out cutting-edge research on various fro
Joined December 2021
RT @ThomasScattoli1: Two birds with one stone! Here you can find the links of our two reviews about the use of Pt-NHC complexes in hydrosil….
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RT @ThomasScattoli1: Excited to see that neutral Pd-NHC allyl complexes possess interesting anticancer properties. Even more surprised that….
pubs.rsc.org
A facile and environmentally friendly method for synthesizing a range of palladium-N-heterocyclic carbene (NHC) complexes—[Pd(NHC)(η3-R-allyl)Cl]—is described. This improved approach, which is based...
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RT @ThomasScattoli1: Our new @EurJIC paper explores novel allyl palladates with potent, selective anticancer activity—outperforming cisplat….
chemistry-europe.onlinelibrary.wiley.com
Novel allyl palladates with diverse azolium ligands exhibit strong cytotoxicity against cancer cells, with some surpassing cisplatin. Compounds with thioether or selenoether groups show the best...
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We’re thrilled to announce that our latest work is now published in Nature Communications! The paper is finally out—go check it out! @discunipd @UniPadova
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RT @ThomasScattoli1: Check out our article in @RSCAdvances dealing with the impact of the charge of PTA-based ligands on the anticancer act….
pubs.rsc.org
In this study, we report the synthesis and characterization of novel organopalladium complexes featuring 1,3,5-triaza-7-phosphaadamantane (PTA)-based ligands, including several cationic derivatives...
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RT @Johannes_Karges: Check out our article in ACS Med. Chem. Lett. @ACSBioMed about the Induction of Ferroptosis with Au(I) NHC Complexes.….
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RT @ThomasScattoli1: Excited to share that, in collaboration with the @Johannes_Karges group, we report first examples of gold-NHC complex….
pubs.acs.org
This study presents the chemical synthesis and biological evaluation of a series of gold(I)-N-heterocyclic carbene complexes as potential anticancer agents. The compounds demonstrated broad activity...
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RT @ThomasScattoli1: Here you can find our lastest work concerning the catalytic and anticancer properties of gold complexes bearing PTA-ba….
pubs.rsc.org
A series of water-soluble gold(i) complexes bearing phosphine ligands, [AuCl(L)] {where L = 1,3,5-triaza-7-phosphaadamantane, PTA (1); 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, DAPTA...
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RT @ThomasScattoli1: First-ever palladium complexes that induce immunogenic cell death are here !.These metal-based warriors don’t just kil….
pubs.rsc.org
Immunogenic cell death (ICD) is a regulated form of cell death that activates an immune response through the release of danger-associated molecular patterns (DAMPs), including calreticulin, ATP, and...
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RT @ThomasScattoli1: Second paper of this 2025! Here you can find the synthesis of Gold and palladium complexes bearing NHC thioglucosides….
chemistry-europe.onlinelibrary.wiley.com
Gold(I) and Palladium(II) Complexes Bearing N-Heterocyclic Carbene Thioglucosides: Synthesis and Antiproliferative Activity Towards Ovarian Cancer Cells. A library of gold(I) and palladium(II)...
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Here you can find our first 2025 contribution! In this work we describe the synthesis of Pd(II) complexes bearing NHC ligands with triazoles as pendant groups. Congrats to Cristina and all the team!
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RT @ThomasScattoli1: Are N-heterocyclic carbenes involved in your research activity? Here you can find a revisitation of the weak base rou….
pubs.rsc.org
Aqueous ammonia has been examined as a new weak base for the synthesis of [Au(NHC)Cl] complexes, as well as for the activation of C–H, S–H, and N–H bonds. Its low cost and mild operational conditions...
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RT @ThomasScattoli1: Are you interested in using machine learning platforms for optimizing new catalytic systems? Here you can find our wor….
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Our new work about the reductive CO2 fixation with amines and hydrosilanes using readily available Cu(II) NHC–phenolate catalyst precursors is now available in @DaltonTrans. Congrats to all the team!
pubs.rsc.org
N-Methylation of amines is of great interest in the synthesis of pharmaceuticals and valuable compounds, and the possibility to perform this reaction with an inexpensive and non-toxic substrate like...
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RT @ThomasScattoli1: Here you can find our work on heterobimetallic Fe(II)/Pd(II) complexes as new promising anticancer agents. Many thanks….
chemistry-europe.onlinelibrary.wiley.com
Synthesis and anticancer properties of heterobimetallic Fe(II)/Pd(II) complexes bearing different butadienyl fragments. The synthesis of novel heterobimetallic Fe(II)/Pd(II) complexes bearing...
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Are you interested in gold(III) catalysis? Here you can find our work on coumarin synthesis in the presence of ionic liquids.
advanced.onlinelibrary.wiley.com
Well-defined (P,C)-cyclometalated Au(III) complexes proved to be able to catalyze the synthesis of coumarins by intramolecular hydroarylation of a broad range of aryl propiolates under mild and...
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Here you can find our latest work dealing with the synthesis of coumarins with an improved gold-based catalytic system.
aces.onlinelibrary.wiley.com
A new catalytic system based on a gold(I) complex in a small amount of a suitable ionic liquid was reported, showing improved performances in gold-catalyzed intramolecular hydroarylations of aryl...
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RT @ThomasScattoli1: Second @ChemicalScience of this 2024! This time we have investigated the impact of both steric and electronic properti….
pubs.rsc.org
Thermally Activated Delayed Fluorescent (TADF) luminophores offer the potential to achieve 100% Internal Quantum Efficiency (IQE) by harvesting both singlet and triplet excitons via reverse intersy...
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RT @ThomasScattoli1: Extremely happy to have contributed to this nice work dealing with th effect of imidazole p-extension on the ECL perfo….
aces.onlinelibrary.wiley.com
We investigate the impact of the π-extension of the imidazole moiety in a series of thermally activated delayed fluorescence emitters on their electrochemical photophysical end electrochemiluminesc...
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RT @ThomasScattoli1: We open this September with a new paper dealing with the synthesis and anticancer activity of Pd-butadienyl complexes….
chemistry-europe.onlinelibrary.wiley.com
Pd(II)-butadienyl complexes bearing picolyl-NHC and phosphine ligands were synthesized and tested towards different cancer cell lines. The best activity was observed on ovarian cancer cells, with a...
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