AKRoesky
@AkRoesky
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Roesky Group @ KIT. Research focus: Lanthanide chemistry, Gold chemistry and catalysis. Account managed by PhD Students.
Karlsruhe
Joined June 2020
We’re happy to present our latest #OpenAccess research article on "Heterobimetallic Cu(I)–Rh(I) and Cu(I)–Ir(I) Complexes: Synthesis, Catalytic Applications in Transfer Hydrogenation, and Photophysical Properties" out now in @EurJIC @ChemEurope:
chemistry-europe.onlinelibrary.wiley.com
Heterobimetallic Cu(I)–Rh(I) and Cu(I)–Ir(I) complexes are synthesized using a phosphine-substituted amidinate ligand via both stepwise and one-pot reactions. The Cu(I)–Ir(I) complex is further...
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Need a read to start of the week? How about our latest #OpenAccess research article on ”Silicon-Based Azo Compound-Mediated CO Activation and N2 Release“ out now in @angew_chem: https://t.co/XUtN3RbEEy
@Faye_94128
onlinelibrary.wiley.com
A rare silicon(IV)-based azo compound featuring a Si─N═N─Si linkage was synthesized via the direct reaction of an organoazide with a silaiminyl–silylene precursor. This compound undergoes an unusual...
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Want to have something for your weekend reading list? How about our latest #OpenAccess paper on "Control over Ba(ii)-mediated single-chain polymer nanoparticle compaction by dynamic metal complexation" out now in @PolymChem :
pubs.rsc.org
The current study investigates the dynamic interactions of barium ions with a synthetic polymer, leading to the formation of intramolecularly folded single-chain nanoparticles (SCNPs), providing...
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Looking for a way to start off the week? How about our new #OpenAccess Advance Article on "Luminescent ionic heterobimetallic diphosphine-β-diketiminate complexes" out now in @DaltonTrans : https://t.co/Fm8VHr1PtA
@Faye_94128
pubs.rsc.org
The syntheses of luminescent heterobimetallic ionic complexes based on the bis(phosphine)-functionalized β-diketiminate ligand [HC{(CH3)C}2{(o-[P(C6H5)2]2C6H4)N}2]− (PNac) are reported. This orthog...
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Happy to share our second #OpenAccess article this week on "On-demand switching from mono-silylene to bis-silylene to access mono-, di- and mixed coinage metal complexes" out now in @ChemicalScience: https://t.co/wOTG5ddFpt
@raviydv01 @Faye_94128
pubs.rsc.org
Recently, we discovered that silaiminyl-silylene, [LSi–Si(NDipp)L] (L = PhC(NtBu)2, Dipp = 2,6-diisopropylphenyl), can be converted from a mono-silylene to bis-silylene by using Lewis acids. This...
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@AkRoesky report a phosphine-functionalized cyclooctatetraene ligand and its inverse sandwich alkali metal complexes. The polymeric architectures vary with the metal ion & crystallization solvent, with an 8-membered ring obtained for Rb! #openaccess 🔓
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Proud to share our latest #OpenAccess research article in @ChemEurJ on "Alkali Metal Complexes of a Phosphine-Functionalized Cyclooctatetraene": https://t.co/isHKkSxWLI
@IqbalJammi @vanitha_naina
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#OnTheCover Synthesis of Molecular Organo-f-Element-Polyphosphides With Non-Classical Divalent Lanthanide Precursors (Peter W. Roesky and co-workers) https://t.co/ybw60JFerC
@AkRoesky • https://t.co/jpfkFusvuW
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#OnTheCover A Novel Synthetic Pathway to Lanthanide Triple-Decker Complexes: Selective Expansion of a Sandwich Complex by an Insertion Reaction (Peter W. Roesky and co-workers) https://t.co/wI7s1hAvjs
@AKRoesky • https://t.co/HRSP5ymaq2
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@AkRoesky and co-workers report the synthesis of organo-f-element-functionalized polyanionic compounds, including a 14-nuclear polyphosphide Zintl anion. The title compounds are the largest organo-f-element polyphosphides known to date #openaccess 🔓
onlinelibrary.wiley.com
Herein we show the synthesis and characterization of organo-f-element-functionalized polyanionic compounds, including the triangular P33− and the P144− polyphosphide Zintl anion. The title compound...
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Introducing Photochemical Action Plots as a Tool for Unlocking On–Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst (Peter W. Roesky and co-workers) @AkRoesky @BarnerKowollik #openaccess 🔓
onlinelibrary.wiley.com
The photochemical action plot methodology developed by the Barner–Kowollik team provides a powerful tool for the investigation of the wavelength dependence of light-driven reactions. Herein, the...
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🔓#OpenAccess #review #coordination Feel free to read Comprehensive coordination chemistry of iminophosphonamides by Bhupendra Goswami and @AkRoesky. 🔗 https://t.co/y7LfRq7YpE
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Come and join in one hour!
Save the date: come and join the first Global Inorganic Virtual Seminar with @TheBartLab and @harder_research! https://t.co/fOuMXz6uKD
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And we are also thrilled to share our latest communication out now in @angew_chem on the "Synthesis of Molecular Organo-f-Element-Polyphosphides with Non-Classical Divalent Lanthanide Precursors": https://t.co/tmHhKHLpM7
onlinelibrary.wiley.com
Herein we show the synthesis and characterization of organo-f-element-functionalized polyanionic compounds, including the triangular P33− and the P144− polyphosphide Zintl anion. The title compound...
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Happy to share our latest research article out now in @angew_chem on "Introducing Photochemical Action Plots as a Tool for Unlocking On-Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst" toghther with @BarnerKowollik and Florian Weigend: https://t.co/qwGirhxkHK
onlinelibrary.wiley.com
The photochemical action plot methodology developed by the Barner–Kowollik team provides a powerful tool for the investigation of the wavelength dependence of light-driven reactions. Herein, the...
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@AKRoesky disclosed a new reaction pathway, in which for the first time a lanthanide half-sandwich unit inserts into an existing sandwich complex. As result a triple decker complex is formed. #openaccess 🔓
onlinelibrary.wiley.com
A new reaction pathway is disclosed, in which for the first time a lanthanide half-sandwich unit inserts into an existing sandwich complex. As a result, a triple-decker complex is formed, which can...
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Save the date: come and join the first Global Inorganic Virtual Seminar with @TheBartLab and @harder_research! https://t.co/fOuMXz6uKD
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And another one! Proud to share our latest #OpenAccess paper on "A Novel Synthetic Pathway to Lanthanide Triple-Decker Complexes: Selective Expansion of a Sandwich Complex by an Insertion Reaction" out now in @angew_chem together with Florian Weigend:
onlinelibrary.wiley.com
A new reaction pathway is disclosed, in which for the first time a lanthanide half-sandwich unit inserts into an existing sandwich complex. As a result, a triple-decker complex is formed, which can...
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